beta,beta,4-三氯苯乙烯合成路线 （共 16 条）
反应条件
1: 86 percent / PbBr2, Al / dimethylformamide / 5 h / Ambient temperature
2: 83 percent / PbBr2, Al, 36percent aq. HCl / methanol / 7 h / 50 - 60 °C
View Scheme
参考文献
Tanaka, Hideo; Yamashita, Shiro; Yamanoue, Motoi; Torii, Sigeru
Journal of Organic Chemistry, 1989 , vol. 54, # 2 p. 444 - 450
反应条件
copper(l) chloride in ammonium hydroxide; dimethyl sulfoxide
T=20°C; 20 h;
参考文献
Korotchenko; Shastin; Nenaidenko; Balenkova
Russian Journal of Organic Chemistry, 2003 , vol. 39, # 4 p. 527 - 531
反应条件
ethylenediamine; copper(l) chloride in ethanol
T=20°C; 24 h;
参考文献
Korotchenko; Shastin; Nenaidenko; Balenkova
Russian Journal of Organic Chemistry, 2003 , vol. 39, # 4 p. 527 - 531
反应条件
ammonia; copper(l) chloride in water; dimethyl sulfoxide
T=20°C; 24 h; Product distribution; Further Variations:CatalystsTemperatures;
参考文献
Shastin; Muzalevskii; Korotchenko; Balenkova; Nenaidenko
Russian Journal of Organic Chemistry, 2006 , vol. 42, # 2 p. 183 - 189
反应条件
ammonia; copper(l) chloride in water; dimethyl sulfoxide
T=20°C; 24 h; Product distribution; Further Variations:CatalystsTemperatures;
参考文献
Shastin; Muzalevskii; Korotchenko; Balenkova; Nenaidenko
Russian Journal of Organic Chemistry, 2006 , vol. 42, # 2 p. 183 - 189
反应条件
n-butyllithium; benzenesulfonyl chloride
1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane , RT, 1 h; Yield given. Multistep reaction;
参考文献
Lee; Shin; Oh
Synthetic Communications, 1991 , vol. 21, # 15-16 p. 1657 - 1661
