tert.-butylnitrite; copper dichloride in acetonitrile T=65°C; 2 h;

暂无反应条件数据

pyridine; (NH4)2S; ethanol

1: 92 percent / CuCl2, tert-butylnitrite / acetonitrile / 2 h / 65 °C 2: 89 percent / Et3N / ethanol / 4 h / Heating 3: 65 percent / hydrazine hydrate / Raney-Ni / ethanol; 1,2-dichloro-ethane / 4 h / 60 °C 4: 78 percent / tetrakis(acetonitrile)copper(I) tetrafluoroborate / toluene / 20 h / 90 °C 5: 90 percent / H2 / Raney-Ni / ethanol; H2O / 1 h / 760 Torr / Ambient temperature View Scheme

pyridine; (NH4)2S; ethanol

1: 92 percent / CuCl2, tert-butylnitrite / acetonitrile / 2 h / 65 °C 2: 89 percent / Et3N / ethanol / 4 h / Heating 3: 65 percent / hydrazine hydrate / Raney-Ni / ethanol; 1,2-dichloro-ethane / 4 h / 60 °C 4: 78 percent / tetrakis(acetonitrile)copper(I) tetrafluoroborate / toluene / 20 h / 90 °C 5: 90 percent / H2 / Raney-Ni / ethanol; H2O / 1 h / 760 Torr / Ambient temperature 6: 85 percent / Ac2O / Ambient temperature 7: 82 percent / LiAlH4 / tetrahydrofuran / 3 h / 0 - 5 °C View Scheme

暂无反应条件数据

ammonia; acetone

sulfuric acid in water T=80°C; 2.5 h;

ethanol; ammonia T=100°C;