in diethyl ether
(N2); to soln. of Fe complex was slowly added soln. of acid chloride at room temp. and mixt. was allowed to stay for 1 - 2 h; chromy. (silica gel, CH2Cl2); first orange Fe thiocomplex was eluted, recrystn. from CH2Cl2/hexane; elem. anal.; red C5H5Fe(CO)2Cl was recrystd. from CH2Cl2/PE; elem. anal.;
参考文献
El-Hinnawi, Mahmoud A.; Al-Ajlouni, Ahmad M.
Journal of Organometallic Chemistry, 1987 , vol. 332, p. 321 - 330
Mukhina, Olga A.; Bhuvan Kumar; Arisco, Teresa M.; Valiulin, Roman A.; Metzel, Greg A.; Kutateladze, Andrei G.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 40 p. 9423 - 9428
1: 82 percent / Et3N / toluene / 3 h / Ambient temperature
2: 40 percent / 750 °C / 0.1 - 1 Torr
View Scheme
参考文献
Aitken, R. Alan; Horsburg, Caroline E. R.; McCreadie, J. Graeme; Seth, Shirley
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 13 p. 1727 - 1732
trans-Pd(Cl)[C(O)Ph](PPh3)2 in tetrahydrofuran
other phenylstannanes;
参考文献
Brown, John M.; Pearson, Mark; Jastrzebski, Johann T. B. H.; Koten, Gerard van
Journal of the Chemical Society, Chemical Communications, 1992 , # 19 p. 1440 - 1441
