hydrogenchloride; tin(ll) chloride Man diazotiert die in Suspension befindliche Zinndoppelverbindung des 3-Amino-salicylaldehyds und traegt die Diazoloesung in die Kupferbromuerloesung ein;
参考文献
Mueller,J.
Chemische Berichte, 1909 , vol. 42, p. 3701
1: N-ethyl-N,N-diisopropylamine / 2-methyl tetrahydrofuran / 0.5 h / 80 °C / Large scale reaction 2: hydrogenchloride; SnCl2·2H2O / tetrahydrofuran; water View Scheme
参考文献
Giubellina, Nicola; Stabile, Paolo; Laval, Gilles; Perboni, Alcide D.; Cimarosti, Zadeo; Westerduin, Pieter; Cooke, Jason W. B.
Organic Process Research and Development, 2010 , vol. 14, # 4 p. 859 - 867
Wijngaarden, Ineke van; Kruse, Chris G.; Heyden, Jan A. M. van der; Tulp, Martin Th. M.
Journal of Medicinal Chemistry, 1988 , vol. 31, # 10 p. 1934 - 1940
1.1: K2CO3; Cs2CO3 / dimethylformamide / 0.17 h / 20 °C
1.2: dimethylformamide / 40 °C
2.1: n-BuLi / tetrahydrofuran / 0.25 h / -78 °C
2.2: tetrahydrofuran / -78 - 20 °C
View Scheme
参考文献
Michrowska, Anna; Bujok, Robert; Harutyunyan, Syuzanna; Sashuk, Volodymyr; Dolgonos, Grigory; Grela, Karol
Journal of the American Chemical Society, 2004 , vol. 126, # 30 p. 9318 - 9325
