potassium permanganate; sodium periodate in water; acetone T=5 - 20°C; 20 h;

C32H12BF24(1-)*C60H80IrNOP(1+); hydrogen; triethylamine in methanol T=45°C; 20 h; AutoclaveHigh pressure; enantioselective reaction;

1.1: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 °C 1.2: 16 h / 0 - 20 °C 2.1: hydrogen; C32H12BF24(1-)*C60H80IrNOP(1+); triethylamine / methanol / 20 h / 45 °C / |Autoclave; |High pressure View Scheme

jones reagent; ozone 1) acetone, -70 deg C, 2) acetone, 1 h, r.t.; Yield given. Multistep reaction. Title compound not separated from byproducts;

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