N-甲基-N-乙烯基苯甲酰胺合成路线 （共 3 条）
反应条件
tri-n-butyl-tin hydride; 1,1'-azobis (cyclohexanecarbonitrile) in toluene
Cyclization; Deiodination; 1 h; Heating;
参考文献
Ishibashi, Hiroyuki; Ohata, Kohei; Niihara, Michiyo; Sato, Tatsunori; Ikeda, Masazumi
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 2000 , vol. 4, p. 547 - 554
反应条件
1: 79 percent / DMAP; Et3N / toluene / 1 h / 20 °C
2: MCPBA / CH2Cl2 / 0.5 h / 0 °C
3: NaHCO3 / xylene / 20 h / Heating
4: 25 percent / Bu3SnH; azobiscyclohexanecarbonitrile / toluene / 1 h / Heating
View Scheme
参考文献
Ishibashi, Hiroyuki; Ohata, Kohei; Niihara, Michiyo; Sato, Tatsunori; Ikeda, Masazumi
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 2000 , vol. 4, p. 547 - 554
反应条件
1: MCPBA / CH2Cl2 / 0.5 h / 0 °C
2: NaHCO3 / xylene / 20 h / Heating
3: 25 percent / Bu3SnH; azobiscyclohexanecarbonitrile / toluene / 1 h / Heating
View Scheme
参考文献
Ishibashi, Hiroyuki; Ohata, Kohei; Niihara, Michiyo; Sato, Tatsunori; Ikeda, Masazumi
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 2000 , vol. 4, p. 547 - 554
