4-甲氧基-4-甲基-联苯合成路线 （共 207 条）
反应条件
Pd0(tris(tert-butyl)phosphine)2; [(pentamethylcyclopentadiene)(PMe3)IrMeCl]; potassium tetrakis(pentafluorophenyl)-borate in water T=100°C; 16 h; Inert atmosphere; regioselective reaction;
参考文献
Organometallics, , vol. 33, # 3 p. 620 - 623
反应条件
1.1: magnesium; lithium chloride / tetrahydrofuran / 40 h / 55 °C / |Inert atmosphere; |Schlenk technique 1.2: |Inert atmosphere; |Schlenk technique 2.1: palladium diacetate; N-[2'-(dicyclohexylphosphino)-1,1'-biphenyl-2-yl]-N,N-dimethylamine / tetrahydrofuran / 1.5 h / 50 °C / |Schlenk technique View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 10 p. 2706 - 2710
Angew. Chem., , vol. 126, # 10 p. 2744 - 2748
反应条件
sulfur T=220 - 240°C;
参考文献
Journal of the Indian Chemical Society, , vol. 26, p. 296,299
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in tetrahydrofuran Suzuki-Miyaura cross-coupling; Heating; Product distribution; Further Variations:Reagents;
参考文献
Organic Letters, , vol. 6, # 1 p. 95 - 98
反应条件
1: sodium perborate tetrahydrate / acetic acid / 3 h / 50 °C 2: 35 percent Chromat. / NiCl2(PPh3)2, p-tolylmagnesium bromide / tetrahydrofuran; diethyl ether / 3 h / Ambient temperature View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 1 p. 7 - 14
反应条件
1: 90 percent / Amberlyst H-15 / diethyl ether / 72 h / -78 - 20 °C 2: 61 percent / sodium hydroxide / ethanol / 3 h / Ambient temperature 3: sodium perborate tetrahydrate / acetic acid / 3 h / 50 °C 4: 35 percent Chromat. / NiCl2(PPh3)2, p-tolylmagnesium bromide / tetrahydrofuran; diethyl ether / 3 h / Ambient temperature View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 1 p. 7 - 14
反应条件
1: 61 percent / sodium hydroxide / ethanol / 3 h / Ambient temperature 2: sodium perborate tetrahydrate / acetic acid / 3 h / 50 °C 3: 35 percent Chromat. / NiCl2(PPh3)2, p-tolylmagnesium bromide / tetrahydrofuran; diethyl ether / 3 h / Ambient temperature View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 1 p. 7 - 14
反应条件
1: 82 percent / NEt3 2: methanol / 1 h / Ambient temperature; Irradiation View Scheme
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 60, # 1.2 p. 1 - 14
反应条件
C30H21F6N2NiO2P in tetrahydrofuran T=70°C; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Catalysis Letters, , vol. 143, # 5 p. 424 - 431
反应条件
1: sodium sulfate / tetrahydrofuran / 24 h / 20 °C / |Schlenk technique; |Inert atmosphere 2: bis-triphenylphosphine-palladium(II) chloride; potassium hydroxide / neat (no solvent) / 24 h / 110 °C / |Schlenk technique; |Inert atmosphere View Scheme
参考文献
Advanced Synthesis and Catalysis, , vol. 355, # 18 p. 3553 - 3557
