Bellut, H.; Koester, R.
Liebigs Annalen der Chemie, 1970 , vol. 738, p. 86 - 96
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Gmelin Handbook: B: B-Verb.4, 4.10, page 208 - 214
Bellut, H.; Koester, R.
Liebigs Annalen der Chemie, 1970 , vol. 738, p. 86 - 96
Full Text Show Details
Gmelin Handbook: B: B-Verb.9, 6.2.2, page 269 - 280
in diethyl ether byproducts: NaCl; dropping soln. of 38 mmol ClB(C2H5)2 in 20 ml diethyl ether to soln. of 37 mmol Na-salt in 40 ml diethyl ether within 20 min under Ar, rise in temp., reflux; refluxing for 4 h;; filtration; complete removal of solvent in vac. at <=40°C; distn. in vac.; product mixt. obtained; (11)B NMR spectroscopy; b. p.;;
ethene; tetraethyldiborane(6)
react. of two equiv of B(C2H5)3 with one equiv of BCl3 at room temp., decompn. of catalyst with ethylene; distn.;
参考文献
Koester, R.; Grassberger, M. A.
Liebigs Annalen der Chemie, 1968 , vol. 719, p. 169 - 186
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Gmelin Handbook: B: B-Verb.9, 6.2.2, page 269 - 280
