2,4,6-三甲基环硼氮烷合成路线 （共 37 条）
参考文献
Noeth,H.; Vahrenkamp,H.
Journal of Organometallic Chemistry, 1969 , vol. 16, p. 357 - 369
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Gmelin Handbook: B: B-Verb.4, 10, page 282 - 288
参考文献
Wiberg; Hertwig; Bolz
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1948 , vol. 256, p. 202,215
反应条件
1: 2,4,6-trimethylborazine With methyllithium in diethyl ether
20 h; Heating;
2: methyl bromide in diethyl ether
48 h; Heating; Title compound not separated from byproducts;
参考文献
Noeth, Heinrich; Rojas-Lima, Susana; Troll, Alexander
European Journal of Inorganic Chemistry, 2005 , # 10 p. 1895 - 1906
反应条件
in diethyl ether
byproducts: LiBr; (Ar or N2), borazine to MeLi 1:2 to 1:3, borazine in Et2O at -78°C treated under stirring with MeLi in Et2O, cooled to -78°C, treated with MeBr in Et2O, refluxed for 2 h; distilled, treated with hexane, filtered, distilled, not isolated, detected by MAS;
参考文献
Noeth, Heinrich; Rojas-Lima, Susana; Troll, Alexander
European Journal of Inorganic Chemistry, 2005 , # 10 p. 1895 - 1906
反应条件
hydrogenchloride; water
byproducts: H2; at 200-250°C for 6 h with 20percent aq. HCl;
参考文献
Schlesinger, H. I.; Horvitz, L.; Burg, A. B.
Journal of the American Chemical Society, 1936 , vol. 58, p. 409 - 414
参考文献
Wiberg; Hertwig; Bolz
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1948 , vol. 256, p. 202,215
参考文献
Wiberg; Hertwig; Bolz
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1948 , vol. 256, p. 202,215
