2,2-二氯-N-辛基-乙酰胺合成路线 （共 4 条）
反应条件
palladium 10 on activated carbon; hydrogen in N,N-dimethyl acetamide
T=25°C; P=760.051 Torr; 2 h; chemoselective reaction;
参考文献
Sawama, Yoshinari; Imanishi, Takahiro; Nakatani, Ryosuke; Fujiwara, Yuta; Monguchi, Yasunari; Sajiki, Hironao
Tetrahedron, 2014 , vol. 70, # 30 p. 4540 - 4546
反应条件
1,2-dichloro-ethane
T=-20 - -10°C;
参考文献
Swensen; Weaver
Journal of the American Chemical Society, 1948 , vol. 70, p. 4060
反应条件
1: 100 percent / acetyl bromide; MeOH / CH2Cl2 / 0.33 h / 25 °C
2: i-Pr2NEt / acetonitrile / 1 h / 25 °C
View Scheme
参考文献
Nazih, Abdesslame; Heissler, Denis
Synthesis, 2002 , # 2 p. 203 - 206
反应条件
1: pentane / 0 - 20 °C
2: palladium 10 on activated carbon; hydrogen / N,N-dimethyl acetamide / 2 h / 25 °C / 760.05 Torr
View Scheme
参考文献
Imanishi, Takahiro; Fujiwara, Yuta; Sawama, Yoshinari; Monguchi, Yasunari; Sajiki, Hironao
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 5 p. 771 - 776
