in water
Kinetics; byproducts: H2O; varying excess of HNO3, 51-75°C; not isolated, reaction followed by chemical analysis and/or volumetry ofN2O;
参考文献
Hughes, Martin N.; Lusty, James R.; Wallis, Helen L.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1978 , p. 530 - 534
in perchloric acid
Kinetics; 2.71-6.78 M HClO4, varying excess of NaNO3, 70°C; not isolated, reaction followed by chemical analysis;
参考文献
Hughes, Martin N.; Lusty, James R.; Wallis, Helen L.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1978 , p. 530 - 534
in neat (no solvent)
heating with amidosulfuric acid at 100 °C; formation of POCl3 and HCl in the distillate and ClSO2NPCl3 containing only traces of Cl2 as residue;;
参考文献
Kirsanov, A. V.
Zh. obshch. Khim., 1952 , vol. 22, p. 88 - 93
C. A., 1952 , p. 6984
Full Text Show Details
Gmelin Handbook: P: MVol.C, 192, page 441 - 443
water in water
hydrolysis described; degree of hydrolysis depending on temp., concn. and time;;
参考文献
Oberhauser, F.; Urbina, H. E.
An. Fac. Fil. Educac. Univ. Chile Secc. Quim, 1946 , vol. 3, p. 119 - 129
C. A., 1947 , p. 1944
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 29, page 1590 - 1593
perchloric acid; sodium sulfate; sodium nitrite in water
Kinetics; with magnetic stirring, at concn. of NH2SO3H and NaNO2 varying from 0.005 to 0.05 M, with acidification with 0.01-0.1 M HClO4 at constant ionic strength of 1 M by Na2SO4; monitored by titrimetry, volumetry, gas analyser and IR spectroscopy;
参考文献
Gladyshev; Kovaleva; Korshunov
Russian Journal of General Chemistry, 2000 , vol. 70, # 9 p. 1340 - 1342
