1: 4-nitrobenzaldehdye; methyl amino(3-chlorophenyl)acetate With (Ra)-2,6-di(anthracen-9-yl)-4-hydroxydinaphtho[1,3,2]dioxaphosphepine 4-oxide in toluene T=50°C; 0.333333 h; Molecular sieve; 2: 1-phenyl-prop-2-yne-1-one in toluene T=50°C; 60 h; Molecular sieve; Overall yield = 32 percent; enantioselective reaction;