B-苄基-9-硼杂双环[3.3.1]壬烷合成路线 （共 22 条）
反应条件
1: 1-benzyl-tetrahydro-thiophenium tetrafluoroborate With lithium hexamethyldisilazane in tetrahydrofuran; dichloromethane
T=-78°C; 1 h;
2: B-benzyl-9-BBN in tetrahydrofuran; dichloromethane
T=-100 - 0°C;
3: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; dichloromethane
T=0 - 20°C; Further stages.;
参考文献
Fang, Guang Y.; Wallner, Olov A.; Di Blasio, Nadia; Ginesta, Xavier; Harvey, Jeremy N.; Aggarwal, Varinder K.
Journal of the American Chemical Society, 2007 , vol. 129, # 47 p. 14632 - 14639
反应条件
water; dihydrogen peroxide; sodium hydroxide in tetrahydrofuran; hexane
T=20°C; 0.5 h; Inert atmosphere;
参考文献
Liu, Lei; Henderson, James A.; Yamamoto, Akihiko; Bremond, Paul; Kishi, Yoshito
Organic Letters, 2012 , vol. 14, # 9 p. 2262 - 2265
