2,5-二(4-甲氧基苯基)-2,5-环己二烯-1,4-二酮合成路线 （共 8 条）
反应条件
1: With palladium (II) trifluoroacetate; silver trifluoromethanesulfonate in tetrahydrofuran; water
T=20°C; 24 h;
2: With FeCl3·6H2O in dichloromethane
T=20°C; 1 h;
参考文献
Ortega, Andrea; Rincon, Angela; Jimenez-Aliaga, Karim L.; Bermejo-Bescos, Paloma; Martin-Aragon, Sagrario; Molina, Maria Teresa; Csaky, Aurelio G.
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 8 p. 2183 - 2187
反应条件
ammonium cerium(IV) nitrate in water; acetonitrile
0.0833333 h;
参考文献
Palmgren, Andreas; Thorarensen, Atli; Baeckvall, Jan-E.
Journal of Organic Chemistry, 1998 , vol. 63, # 11 p. 3764 - 3768
反应条件
sodium acetate in N,N-dimethyl-formamide
1.5 h; Ambient temperature;
参考文献
Takahashi, Ichiro; Muramatsu, Osamu; Fukuhara, Jun; Hosokawa, Yoshinao; Takeyama, Naohiko; et al.
Chemistry Letters, 1994 , # 3 p. 465 - 468
反应条件
1: 1.) t-BuLi, ZnCl2, 2.) Pd(PPh3)4 / 1.) THF, -78 deg C, 1 h; room temperature, 2 h; room temperature, 1 h, 2.) THF, 55 deg C, 12 h
2: 92 percent / CAN / H2O; acetonitrile / 0.08 h
View Scheme
参考文献
Palmgren, Andreas; Thorarensen, Atli; Baeckvall, Jan-E.
Journal of Organic Chemistry, 1998 , vol. 63, # 11 p. 3764 - 3768
反应条件
1: 88 percent / Br2 / acetic acid / 2 h / Ambient temperature
2: 1.) t-BuLi, ZnCl2, 2.) Pd(PPh3)4 / 1.) THF, -78 deg C, 1 h; room temperature, 2 h; room temperature, 1 h, 2.) THF, 55 deg C, 12 h
3: 92 percent / CAN / H2O; acetonitrile / 0.08 h
View Scheme
参考文献
Palmgren, Andreas; Thorarensen, Atli; Baeckvall, Jan-E.
Journal of Organic Chemistry, 1998 , vol. 63, # 11 p. 3764 - 3768
反应条件
carbon disulfide; aluminium trichloride
T=0°C; durch Kondensation; und Kochen des Reaktionsprodukts mit Eisenchlorid in Eisessig;
参考文献
Pummerer; Prell
Chemische Berichte, 1922 , vol. 55, p. 3114
Full Text Show Details
Pummerer
Patent: DE459739 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 16, p. 419
反应条件
1: acetic acid; acetic acid anhydride; nitros gases
2: ethanol; ethyl acetate
View Scheme
参考文献
Akagi; Hirose
Yakugaku Zasshi, 1942 , vol. 62, p. 191,193
Chem.Abstr., 1951 , p. 6169
反应条件
ethanol; ethyl acetate
参考文献
Akagi; Hirose
Yakugaku Zasshi, 1942 , vol. 62, p. 191,193
Chem.Abstr., 1951 , p. 6169
