1,3,5-三羟基-4-异戊二烯氧蒽酮合成路线 （共 5 条）
反应条件
1: oxalyl chloride / CH2Cl2 / 3 h / 20 °C
2: 86 percent / AlCl3 / CH2Cl2 / 15 h / 20 °C
3: 93 percent / pyridine; aq. tetramethylammonium hydroxide / 4 h / Heating
4: 95 percent / aq. HI; phenol / 24 h / Heating
5: 13 percent / aq. KOH / 16 h / 20 °C
View Scheme
参考文献
Helesbeux, Jean-Jacques; Duval, Olivier; Dartiguelongue, Caroline; Seraphin, Denis; Oger, Jean-Michel; Richomme, Pascal
Tetrahedron, 2004 , vol. 60, # 10 p. 2293 - 2300
反应条件
1: 86 percent / AlCl3 / CH2Cl2 / 15 h / 20 °C
2: 93 percent / pyridine; aq. tetramethylammonium hydroxide / 4 h / Heating
3: 95 percent / aq. HI; phenol / 24 h / Heating
4: 13 percent / aq. KOH / 16 h / 20 °C
View Scheme
参考文献
Helesbeux, Jean-Jacques; Duval, Olivier; Dartiguelongue, Caroline; Seraphin, Denis; Oger, Jean-Michel; Richomme, Pascal
Tetrahedron, 2004 , vol. 60, # 10 p. 2293 - 2300
反应条件
potassium hydroxide
T=20°C; 16 h;
参考文献
Helesbeux, Jean-Jacques; Duval, Olivier; Dartiguelongue, Caroline; Seraphin, Denis; Oger, Jean-Michel; Richomme, Pascal
Tetrahedron, 2004 , vol. 60, # 10 p. 2293 - 2300
反应条件
1: 95 percent / aq. HI; phenol / 24 h / Heating
2: 13 percent / aq. KOH / 16 h / 20 °C
View Scheme
参考文献
Helesbeux, Jean-Jacques; Duval, Olivier; Dartiguelongue, Caroline; Seraphin, Denis; Oger, Jean-Michel; Richomme, Pascal
Tetrahedron, 2004 , vol. 60, # 10 p. 2293 - 2300
反应条件
1: 93 percent / pyridine; aq. tetramethylammonium hydroxide / 4 h / Heating
2: 95 percent / aq. HI; phenol / 24 h / Heating
3: 13 percent / aq. KOH / 16 h / 20 °C
View Scheme
参考文献
Helesbeux, Jean-Jacques; Duval, Olivier; Dartiguelongue, Caroline; Seraphin, Denis; Oger, Jean-Michel; Richomme, Pascal
Tetrahedron, 2004 , vol. 60, # 10 p. 2293 - 2300
