三环[10.4.0.04,9]十六烷-1(16),4(9),5,7,10,12,14-庚烯-2-炔合成路线 （共 7 条）
反应条件
in hexane 60 h; Ambient temperature;
参考文献
Ho, Mei Sing; Wong, Henry N. C.
Journal of the Chemical Society, Chemical Communications, 1989 , # 17 p. 1238 - 1240
反应条件
potassium tert-butylate in tetrahydrofuran
0.0166667 h; Ambient temperature;
参考文献
Graaff, Rudolf A.G. de; Gorter, Sybout; Romers, Cornelius; Wong, Henry N.C.; Sondheimer, Franz
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1981 , p. 478 - 480
反应条件
potassium tert-butylate in tetrahydrofuran
0.0833333 h; Ambient temperature;
参考文献
Song, Zhi Zhong; Ho, Mei Sing; Wong, Henry N. C.
Journal of Organic Chemistry, 1994 , vol. 59, # 14 p. 3917 - 3926
反应条件
1: 60 percent / 2,6-di-tert-butyl-4-methylpyridine / CH2Cl2 / 20 °C
2: 80 percent / t-BuOK / tetrahydrofuran / 0 °C
View Scheme
参考文献
Chaffins, Sterling; Brettreich, Michael; Wudl, Fred
Synthesis, 2002 , # 9 p. 1191 - 1194
反应条件
1: 70 percent / BF3*Et2O / CH2Cl2 / 2 h / -10 °C
2: 60 percent / 2,6-di-tert-butyl-4-methylpyridine / CH2Cl2 / 20 °C
3: 80 percent / t-BuOK / tetrahydrofuran / 0 °C
View Scheme
参考文献
Chaffins, Sterling; Brettreich, Michael; Wudl, Fred
Synthesis, 2002 , # 9 p. 1191 - 1194
反应条件
1: H2 / Pt
2: Br2 / Irradiation
3: KOtBu / tetrahydrofuran
4: H2 / Pt
View Scheme
参考文献
Wong,H.N.C. et al.
Journal of the American Chemical Society, 1974 , vol. 96, # 17 p. 5604 - 5605
反应条件
1: H2 / Pt
2: Br2 / Irradiation
3: KOtBu / tetrahydrofuran
View Scheme
参考文献
Wong,H.N.C. et al.
Journal of the American Chemical Society, 1974 , vol. 96, # 17 p. 5604 - 5605
