(S)-(+)-2-甲基溴丁烷合成路线 （共 39 条）
参考文献
Journal of the Indian Chemical Society, , vol. 46, p. 995 - 996
反应条件
1.1: Mg / diethyl ether 1.2: CuI / -50 - 20 °C 2.1: BH3 / tetrahydrofuran / 5 h / 20 °C 2.2: 2.7 g / 1 M aq. NaOH; 35 percent H2O2 / tetrahydrofuran / 2 h / 20 °C View Scheme
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
反应条件
1: 50 percent / various solvent(s) / 24 h / 85 °C 2: 90 percent / 1 N HCl / various solvent(s) 3: 69 percent / KOH View Scheme
参考文献
Anteunis, M. J. O.; Callens, R.; Witte, M. De; Reyniers, M. F.; Spiessens, L.
Bulletin des Societes Chimiques Belges, 1987 , vol. 96, # 7 p. 545 - 554
反应条件
durch Hitze Umlagerung;
参考文献
Michael; Leupold
Justus Liebigs Annalen der Chemie, 1911 , vol. 379, p. 321
反应条件
iodine; magnesium in tetrahydrofuran; nitrogen
参考文献
Takasago International Corporation
Patent: US6093345 A1, 2000 ;
反应条件
iodine; magnesium in diethyl ether 1.) reflux, 1 h; 2.) -5 deg C, 2-3 h;
参考文献
Desai; Pathak
Journal of the Indian Chemical Society, 1984 , vol. 61, # 9 p. 814 - 816
反应条件
phenyl-sodium T=0°C; Erwaermen des Reaktionsgemisches auf Raumtemperatur;
参考文献
Letsinger
Journal of the American Chemical Society, 1948 , vol. 70, p. 408
参考文献
Letsinger
Journal of the American Chemical Society, 1948 , vol. 70, p. 408
反应条件
T=184°C; bei laengerem Erhitzen des entstehenden 2-Brom-2-methyl-butans; dextrorotatory form of 1-bromo-2-methyl-butane;
参考文献
Michael; Zeidler
Justus Liebigs Annalen der Chemie, 1911 , vol. 385, p. 285
反应条件
1: 50 percent / various solvent(s) / 24 h / 85 °C 2: 90 percent / 1 N HCl / various solvent(s) 3: 69 percent / KOH 4: 84 percent / sat. Na2CO3 / diethyl ether / 0.5 h 5: 95 percent / electrolyte Bu4NBF4 / 1.13 h / 10 °C / Pt-anode 6: SnCl4 / H2O / 48 h / Ambient temperature 7: 12 N HCl, DOWEX 50(H+) / 24 h / 100 - 110 °C View Scheme
参考文献
Anteunis, M. J. O.; Callens, R.; Witte, M. De; Reyniers, M. F.; Spiessens, L.
Bulletin des Societes Chimiques Belges, 1987 , vol. 96, # 7 p. 545 - 554
