in neat (no solvent) amorphous and platelet Cs2O react vigorously with CO2;
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 27 p. 4169 - 4172
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反应条件
in water Nitridotechnetic(VI) acid was added to a soln. of CsOH*H2O in water, shaking and further water addn.;; filtration, ethanol addn. pptd. a yellow powder, centrifugn., ppt. twice resuspended in ethanol, recentrifugn. dried in vacuum; elem. anal.;
参考文献
Baldas, John; Boas, John F.; Bonnyman, John; Colmanet, Silvano F.; Williams, Geoffrey A.
Inorganica Chimica Acta, 1991 , vol. 179, p. 151 - 154
hydrogen sulfide; nitric acid in water hydrolysis of 3CsCl * 2SbCl3 by heating; pptn. of Sb with H2S; evapn. of the filtrate with HNO3, calcination with oxalic acid (double amt.); filtration, extn. with ethanol;
参考文献
Industrial and Engineering Chemistry, , vol. 16, p. 1280 - 1280
in not given a boiling soln. of Cs2SO4 was treated with Ba(OH)2, the forming soln. of BaOH was reduced in volume, crystn. of aq. Cs2CO3, on heating these crystals melt in their hydrate water leaving anhydrous Cs2CO3 back;;
in neat (no solvent) CsHCO3 was heated for several hours in an indifferent stream of gas at 175 °C forming Cs2CO3;;
参考文献
Forcrand, de
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 149, p. 719 - 719
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Gmelin Handbook: Cs: MVol.2, 67, page 235 - 237
in neat (no solvent) Kinetics; heating in air up to 600°C under atmospheric pressure and humidity (heating rate 5-10°C/min); thermogravimetric monitoring;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 52, p. 1063 - 1067
Zhurnal Obshchei Khimii, , vol. 52, p. 1209 - 1213
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反应条件
in neat (no solvent) byproducts: CO, COS, caesium pentasulfide; Cs2S was heated in a dry stream of CO2 at 350 °C with formation of Cs2CO3 beside Cs2SO4 and caesium pentasulfide;;
参考文献
Annales de Chimie (Cachan, France), , vol. 2, p. 209 - 209
