2,2,4-三甲基-4-硝基戊烷合成路线 （共 13 条）
反应条件
in dimethyl sulfoxide
T=25°C; 2 h; Rate constantKinetics;
参考文献
Katritzky, Alan R.; Kashmiri, M. Akram; Ville, George Z. de; Patel, Ranjan C.
Journal of the American Chemical Society, 1983 , vol. 105, # 1 p. 90 - 96
反应条件
T=145°C; Prod.5:Pivalinsaeure; Prod.6:3,3-Dimethyl-buttersaeure; Prod.7:2,2-Dimethyl-bernsteinsaeure;
参考文献
Nametkin; Sabrodina
Doklady Akademii Nauk SSSR, 1950 , vol. 75, p. 395,543, 701
Chem.Abstr., 1951 , p. 6998,6999,7519
反应条件
1: 64 percent / amalgamated aluminum / diethyl ether / 1 h
2: 85 percent / sodium hydroxide / H2O; hexane / 0.17 h
3: 54 percent / hexane / 2 h / 80 °C
4: 60 percent / H2 / 5percent Pd/C / hexane / 72 h / 1551.4 Torr
View Scheme
参考文献
Stowell, John C.; Lau, Chun M
Journal of Organic Chemistry, 1986 , vol. 51, # 17 p. 3355 - 3357
