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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
53475-25-5
合成路线
（共 9 条）
622-76-4
1-苯基-1-丁炔
+
59-88-1
盐酸苯肼
→
反应条件
53475-25-5
反应条件
[(η5-C5Me5)2Rh2(μ-Cl)2Cl2]; sodium acetate; acetic acid; pentan-3-one in ethanol T=110°C; 20 h; Sealed tubeInert atmosphere; regioselective reaction;
参考文献
Muralirajan, Krishnamoorthy; Cheng, Chien-Hong
Advanced Synthesis and Catalysis, 2014 , vol. 356, # 7 p. 1571 - 1576
622-76-4
1-苯基-1-丁炔
+
114-83-0
1-乙酰基-2-苯基肼
→
反应条件
53475-25-5
反应条件
[{(η5-C5Me5)RhCl}2(μ-Cl)2]; caesium acetate; acetic acid in 1,2-dichloro-ethane T=100°C; 16 h; Inert atmosphere;
参考文献
Zhao, Dongbing; Shi, Zhuangzhi; Glorius, Frank
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12426 - 12429
Angew. Chem., 2013 , vol. 125, # 47 p. 12652 - 12656,4
74497-02-2
→
反应条件
53475-25-5
反应条件
1: hydrogenchloride; sodium nitrite; tin(ll) chloride / water / 0.75 h / 0 - 5 °C / |Inert atmosphere 2: sodium hydroxide / tetrahydrofuran / 0.5 h / |Inert atmosphere 3: [(η5-C5Me5)2Rh2(μ-Cl)2Cl2]; caesium acetate; acetic acid / 1,2-dichloro-ethane / 16 h / 100 °C / |Inert atmosphere View Scheme
参考文献
Zhao, Dongbing; Shi, Zhuangzhi; Glorius, Frank
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12426 - 12429
Angew. Chem., 2013 , vol. 125, # 47 p. 12652 - 12656,4
54431-10-6
→
反应条件
53475-25-5
反应条件
nickel dichloride T=200 - 240°C;
参考文献
Korczynski; Brydowna; Kierzek
Gazzetta Chimica Italiana, 1926 , vol. 56, p. 905
71149-35-4
→
反应条件
53475-25-5
+
73822-07-8
反应条件
sodium tetrahydroborate in methanol 2.5 h; Ambient temperature;
参考文献
Berti, Corrado; Greci, Lucedio; Poloni, Marino; Andreetti, Giovanni Dario; Bocelli, Gabriele; Sgarabotto, Paolo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 339 - 346
59-88-1
盐酸苯肼
→
反应条件
53475-25-5
反应条件
1: sodium hydroxide / tetrahydrofuran / 0.5 h / |Inert atmosphere 2: [{(η5-C5Me5)RhCl}2(μ-Cl)2]; caesium acetate; acetic acid / 1,2-dichloro-ethane / 16 h / 100 °C / |Inert atmosphere View Scheme
参考文献
Zhao, Dongbing; Shi, Zhuangzhi; Glorius, Frank
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12426 - 12429
Angew. Chem., 2013 , vol. 125, # 47 p. 12652 - 12656,4
71149-35-4
→
反应条件
53475-25-5
反应条件
hydrogenchloride; sodium tetrahydroborate 1.) MeOH, room temperature, 2.5 h, 2.) EtOH, room temperature, 2.5 h; Yield given. Multistep reaction;
参考文献
Berti, Corrado; Greci, Lucedio; Poloni, Marino; Andreetti, Giovanni Dario; Bocelli, Gabriele; Sgarabotto, Paolo
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 339 - 346
622-76-4
1-苯基-1-丁炔
+
615-43-0
2-碘苯胺
→
反应条件
53475-25-5
+
78825-91-9
反应条件
Yield givenMultistep reaction;
参考文献
Smith, Adrian L.; Stevenson, Graeme I.; Swain, Christopher J.; Castro, Jose L.
Tetrahedron Letters, 1998 , vol. 39, # 45 p. 8317 - 8320
53475-25-5
+
68-12-2
N,N-二甲基甲酰胺
→
反应条件
83824-11-7
反应条件
trichlorophosphate T=100°C; 3 h;
参考文献
Biswas, K. M.; Dhara, R. N.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1982 , vol. 21, # 7 p. 632 - 637
