4,4,5,5,6,6,6-七氟-1-苯基-1,3-己二酮合成路线 （共 8 条）
反应条件
1: ethyl 2,2,3,3,4,4,4-heptafluorobutyrate With sodium methylate in methanol; diethyl ether T=0°C; 0.5 h; 2: acetophenone in methanol; diethyl ether T=20°C; Claisen condensation; 16 h; Further stages.;
参考文献
Buettner, Stefan; Lubbe, Mathias; Reinke, Helmut; Fischer, Christine; Langer, Peter
Tetrahedron, 2008 , vol. 64, # 34 p. 7968 - 7976
反应条件
sodium hydride in diethyl ether
参考文献
Peglion, Jean-Louis; Pastor, Raphael-Emile; Cambon, Aime-Roger
Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 5-6 p. 309 - 315
反应条件
4-toluenesulfonyl azide; triethylamine in dichloromethane 5 h;
参考文献
Nikolaev, V. A.; Utkin, P. Yu.; Korobitsyna, I. K.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 6.1 p. 1059 - 1061
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 6 p. 1176 - 1179
反应条件
4-toluenesulfonyl azide; triethylamine in dichloromethane 5 h;
参考文献
Nikolaev, V. A.; Utkin, P. Yu.; Korobitsyna, I. K.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 6.1 p. 1059 - 1061
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 6 p. 1176 - 1179
反应条件
triethylamine; dibromotriphenyl-phosphorane in dichloromethane
T=20°C; 4 h; or triphenylphosphine dichloride, other time; Yield given. Yields of byproduct given;
参考文献
Chechulin, P. I.; Filyakova, V. I.; Pashkevich, K. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 1.2 p. 189 - 190
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , vol. 38, # 1 p. 203 - 204
反应条件
triethylamine; dibromotriphenyl-phosphorane in dichloromethane
T=20°C; 4 h; or triphenylphosphine dichloride, other time; Yield given. Yields of byproduct given;
参考文献
Chechulin, P. I.; Filyakova, V. I.; Pashkevich, K. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 1.2 p. 189 - 190
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , vol. 38, # 1 p. 203 - 204
反应条件
hydrogenchloride; hydrazine in methanol
T=60°C; 3 h; Heating;
参考文献
Peglion, Jean-Louis; Pastor, Raphael-Emile; Cambon, Aime-Roger
Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 5-6 p. 309 - 315
反应条件
triethylamine; dibromotriphenyl-phosphorane in dichloromethane
T=20°C; 4 h; or triphenylphosphine dichloride, other time; Yield given. Yields of byproduct given;
参考文献
Chechulin, P. I.; Filyakova, V. I.; Pashkevich, K. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 1.2 p. 189 - 190
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , vol. 38, # 1 p. 203 - 204
