ClRh(P(CH2CH2(CF2)5CF3)3)3 in further solvent(s) inert atmosphere; 40°C (12 h), cooling (room temp.); extg. (toluene), evapn. (vac.), chromy. (hexanes/ether=98:2); isolated as mixture of isomers, detd. by (1)H and (13)C NMR spectroscopy;
参考文献
Cid, Jessica; Carbo, Jorge J.; Fernandez, Elena
Chemistry - A European Journal, 2012 , vol. 18, # 5 p. 1512 - 1521
triethylamine; Rh olefin ligated to 1,3-dimethyl-4-CF3-imidazolylidene in tetrahydrofuran T=25°C; 14 h; Title compound not separated from byproducts.;
参考文献
Khramov, Dimitri M.; Rosen, Evelyn L.; Er, Joyce A.V.; Vu, Peter D.; Lynch, Vincent M.; Bielawski, Christopher W.
Tetrahedron, 2008 , vol. 64, # 29 p. 6853 - 6862
1: With NiCl2((PPh3)P)2; diisobutylaluminium hydride in tetrahydrofuran T=22°C; 2 h; Inert atmosphere; 2: With MeOB(pin) in tetrahydrofuran T=22°C; 24 h;
参考文献
Gao, Fang; Hoveyda, Amir H.
Journal of the American Chemical Society, 2010 , vol. 132, # 32 p. 10961 - 10963
potassium acetate; copper(l) chloride; lithium chloride in N,N-dimethyl-formamide (N2); addn. of DMF and LiCl to CuCl, stirring for 1 h at room temp., addn. of boron compd. and alkyne, stirring at room temp. for 16 h, addn. ofwater; extn. with benzene, washing with water, drying with MgSO4, column chromy(SiO2);
参考文献
Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio
Journal of Organometallic Chemistry, 2001 , vol. 625, # 1 p. 47 - 53
