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乙二醇
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63148-62-9
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二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
苯乙炔
合成路线
(共 4628 条)
77152-08-0
+
536-74-3
苯乙炔
→
反应条件
772-62-3
反应条件
N,N,N',N,-tetramethylethylenediamine; triethyl amine hydrochloride in N,N-dimethyl-formamide T=20°C; 1 h;
参考文献
Serizawa, Hiroki; Aikawa, Kohsuke; Mikami, Koichi
Chemistry - A European Journal, 2013 , vol. 19, # 52 p. 17692 - 17697
536-74-3
苯乙炔
→
反应条件
772-62-3
反应条件
tris[fac-2-phenylpyridinato-C2,N]iridium(III); caesium carbonate in N,N-dimethyl-formamide T=20°C; 12 h; Sealed tubeInert atmosphereIrradiation;
参考文献
Iqbal, Naeem; Jung, Jaehun; Park, Sehyun; Cho, Eun Jin
Angewandte Chemie - International Edition, 2014 , vol. 53, # 2 p. 539 - 542
Angew. Chem., 2014 , vol. 126, # 2 p. 549 - 552
1058685-73-6
+
536-74-3
苯乙炔
→
反应条件
772-62-3
反应条件
1: phenylacetylene With n-butyllithium in tetrahydrofuran T=0°C; 0.25 h; Inert atmosphere; 2: N,N-(dimethylamino)-S-phenyl-S-trifluoromethyloxosulfonium trifluoromethanesulfonate in tetrahydrofuran T=-78 - 20°C; 2 h; Inert atmosphere;
参考文献
Urban, Celine; Cadoret, Frederic; Blazejewski, Jean-Claude; Magnier, Emmanuel
European Journal of Organic Chemistry, 2011 , # 25 p. 4862 - 4867
81290-20-2
(三氟甲基)三甲基硅烷
+
536-74-3
苯乙炔
→
反应条件
772-62-3
+
2002-89-3
反应条件
sulfur; potassium fluoride in N,N-dimethyl-formamide T=20°C; 6 h; Air;
参考文献
Chen, Chao; Chu, Lingling; Qing, Feng-Ling
Journal of the American Chemical Society, 2012 , vol. 134, # 30 p. 12454 - 12457
81290-20-2
(三氟甲基)三甲基硅烷
+
536-74-3
苯乙炔
→
反应条件
886-66-8
1,4-二苯基丁二炔
+
772-62-3
反应条件
potassium fluoride; copper(l) iodide in N,N-dimethyl-formamide T=100°C;
参考文献
Chu, Lingling; Qing, Feng-Ling
Journal of the American Chemical Society, 2010 , vol. 132, # 21 p. 7262 - 7263
536-74-3
苯乙炔
→
反应条件
772-62-3
反应条件
[2,2']bipyridinyl; copper(l) iodide; potassium carbonate in N,N-dimethyl-formamide T=60°C; 6 h;
参考文献
Wang, Xiaoping; Lin, Jinhong; Zhang, Chengpan; Xiao, Jichang; Zheng, Xing
Chinese Journal of Chemistry, 2013 , vol. 31, # 7 p. 915 - 920
2314-97-8
三氟碘甲烷
+
536-74-3
苯乙炔
→
反应条件
41879-17-8
+
772-62-3
反应条件
tris[fac-2-phenylpyridinato-C2,N]iridium(III); potassium tert-butylate in N,N-dimethyl-formamide T=20°C; 12 h; Sealed tubeInert atmosphereIrradiation; Reagent/catalystSolvent;
参考文献
Iqbal, Naeem; Jung, Jaehun; Park, Sehyun; Cho, Eun Jin
Angewandte Chemie - International Edition, 2014 , vol. 53, # 2 p. 539 - 542
Angew. Chem., 2014 , vol. 126, # 2 p. 549 - 552
111-50-2
己二酰氯
+
536-74-3
苯乙炔
→
反应条件
77267-31-3
反应条件
MnI2; n-butyllithium in tetrahydrofuran; hexane T=-20°C; 1 h;
参考文献
Fouad, Farid S.; Wright, Justin M.; Plourde II, Gary; Purohit, Ajay D.; Wyatt, Justin K.; El-Shafey, Ahmed; Hynd, George; Crasto, Curtis F.; Lin, Yiqing; Jones, Graham B.
Journal of Organic Chemistry, 2005 , vol. 70, # 24 p. 9789 - 9797
536-74-3
苯乙炔
+
904743-82-4
→
反应条件
77267-31-3
反应条件
n-butyllithium in tetrahydrofuran; hexane T=0 - 20°C;
参考文献
Fouad, Farid S.; Wright, Justin M.; Plourde II, Gary; Purohit, Ajay D.; Wyatt, Justin K.; El-Shafey, Ahmed; Hynd, George; Crasto, Curtis F.; Lin, Yiqing; Jones, Graham B.
Journal of Organic Chemistry, 2005 , vol. 70, # 24 p. 9789 - 9797
→
反应条件
77267-31-3
反应条件
1: phenylacetylene With n-butyllithium 2: adipic acid diethyl ester With boron trifluoride diethyl etherate
参考文献
Wessig, Pablo; Mueller, Gunnar; Kuehn, Andreas; Herre, Robert; Blumenthal, Haiko; Troelenberg, Stefanie
Synthesis, 2005 , # 9 art. no. C01705SS, p. 1445 - 1454
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