1,2,3-三碘-5-硝基苯合成路线 （共 10 条）
反应条件
hydrogenchloride; acetone; tin(ll) chloride
参考文献
Willgerodt; Arnold
Chemische Berichte, 1901 , vol. 34, p. 3349
Full Text Show Details
Kalb et al.
Chemische Berichte, 1926 , vol. 59, p. 1864
参考文献
Willgerodt; Arnold
Chemische Berichte, 1901 , vol. 34, p. 3349
Full Text Show Details
Kalb et al.
Chemische Berichte, 1926 , vol. 59, p. 1864
参考文献
Koerner; Contardi
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1913 , vol. <5> 22 I, p. 823
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1914 , vol. <5> 23 I, p. 283 Anm.
参考文献
Koerner; Contardi
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1913 , vol. <5> 22 I, p. 823
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1914 , vol. <5> 23 I, p. 283 Anm.
反应条件
1: potassium carbonate; butanone 2: aq.-ethanolic NaOH-solution 3: aq. NaOH solution / anschliessendes Erwaermen mit Eisen(II)-sulfat und Bariumhydroxid 4: palladium; aq.-ethanolic NaOH-solution / Hydrogenation 5: aqueous hydrochloric acid; sodium nitrite / Erhitzen der Reaktionsloesung mit wss. Salzsaeure View Scheme
参考文献
Canzanelli; Harington; Randall
Biochemical Journal, 1934 , vol. 28, p. 68,71
反应条件
1: With sulfuric acid; acetic acid; sodium nitrite
T=25°C;
2: With potassium iodide
T=85 - 90°C; Further stages.;
参考文献
Zhang, Xin; Chen, Zhijian; Wuerthner, Frank
Journal of the American Chemical Society, 2007 , vol. 129, # 16 p. 4886 - 4887
反应条件
1.1: 61 percent / ICl; aq. H2SO4 / 2 h / 80 °C
2.1: NaNO2; aq. H2SO4; AcOH / 25 °C
2.2: 91 percent / aq. KI / 85 - 90 °C
View Scheme
参考文献
Zhang, Xin; Chen, Zhijian; Wuerthner, Frank
Journal of the American Chemical Society, 2007 , vol. 129, # 16 p. 4886 - 4887
反应条件
iodine; periodic acid in sulfuric acid
1.) room temperature, 1 d, 2.) 75 deg C, 1 d;
参考文献
Mattern, Daniell Lewis
Journal of Organic Chemistry, 1984 , vol. 49, # 17 p. 3051 - 3053
反应条件
reagent "I(1+)" in sulfuric acid
T=100°C; Iodination; 0.5 h; Product distribution; Further Variations:Temperatures;
参考文献
Chaikovskii, V. K.; Kharlova, T. S.; Filimonov, V. D.
Russian Chemical Bulletin, 1999 , vol. 48, # 7 p. 1291 - 1294
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1999 , # 7 p. 1303 - 1306
反应条件
1: 93 percent / Et3N; CuI / Pd(PPh3)2Cl2 / 4 h / 80 °C
2: 53 percent / H2 / Pd/C / ethanol; ethyl acetate / 24 h / 20 °C
View Scheme
参考文献
Chen, Zhijian; Stepanenko, Vladimir; Dehm, Volker; Prins, Paulette; Siebbeles, Laurens D. A.; Seibt, Joachim; Marquetand, Philipp; Engel, Volker; Wuerthner, Frank
Chemistry - A European Journal, 2007 , vol. 13, # 2 p. 436 - 449
