1-乙烯基-3,5-二甲基-苯合成路线 （共 9 条）
参考文献
v. Braun; Engel
Chemische Berichte, 1925 , vol. 58, p. 283
反应条件
aluminum oxide
T=320°C; P=30 Torr;
参考文献
Sianesi
Gazzetta Chimica Italiana, 1959 , vol. 89, p. 1749,1759
Full Text Show Details
Schwartzman; Corson
Journal of the American Chemical Society, 1956 , vol. 78, p. 322,324
反应条件
1: 1-bromo-3,5-dimethyl-benzene With magnesium; ethylene dibromide in diethyl ether
2: trans vinyl bromide With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether
T=0°C; 2 h;
参考文献
Hirose, Keiji; Aksharanandana, Pakatip; Suzuki, Michiko; Wada, Kiyoshi; Naemura, Koichiro; Tobe, Yoshito
Heterocycles, 2005 , vol. 66, # 1 p. 405 - 431
反应条件
1,3-bis-(diphenylphosphino)propane; palladium diacetate in N,N-dimethyl-formamide
T=150°C; oxidative Heck reaction; 0.0333333 h;
参考文献
Odell, Luke R.; Lindh, Jonas; Gustafsson, Tomas; Larhed, Mats
European Journal of Organic Chemistry, 2010 , # 12 p. 2270 - 2274
反应条件
1: LiAlH4
2: Al2O3 / 320 °C / 30 Torr
View Scheme
参考文献
Sianesi
Gazzetta Chimica Italiana, 1959 , vol. 89, p. 1749,1759
Full Text Show Details
Schwartzman; Corson
Journal of the American Chemical Society, 1956 , vol. 78, p. 322,324
反应条件
1: 1) anhydrous sodium sulfite 2) dimethylformamide, thionyl chloride / 1) water, reflux, 24 h 2) benzene, reflux, 4h
2: 70 percent / Sodium azide / acetone; H2O / 12 h / Ambient temperature
3: 3.8 percent / 0 h / 400 °C / 3.7 - 3.8 Torr
View Scheme
参考文献
Abramovitch, Rudolph A.; Holcomb, William D.; Thompson, W. Marshall; Wake, Shigeo
Journal of Organic Chemistry, 1984 , vol. 49, # 26 p. 5124 - 5131
反应条件
1: 70 percent / Sodium azide / acetone; H2O / 12 h / Ambient temperature
2: 3.8 percent / 0 h / 400 °C / 3.7 - 3.8 Torr
View Scheme
参考文献
Abramovitch, Rudolph A.; Holcomb, William D.; Thompson, W. Marshall; Wake, Shigeo
Journal of Organic Chemistry, 1984 , vol. 49, # 26 p. 5124 - 5131
反应条件
T=400°C; P=3.7 - 3.8 Torr; 3.75 h;
参考文献
Abramovitch, Rudolph A.; Holcomb, William D.; Thompson, W. Marshall; Wake, Shigeo
Journal of Organic Chemistry, 1984 , vol. 49, # 26 p. 5124 - 5131
反应条件
T=640 - 650°C; beim Leiten durch ein Rohr;
参考文献
Naugatuck Chemical Co.
Patent: DE476270 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 16, p. 331
