1,2-二对甲苯基乙烷合成路线 (共 169 条)
反应条件
Ambient temperatureIrradiationrelative yields of products for different substituents;
参考文献
Tetrahedron, , vol. 41, # 8 p. 1435 - 1440
反应条件
perchloric acid; hexaoxo-.mu.-peroxodisulfate(2-); Cu(II) perchlorate in water; acetonitrile T=83°C; 0.416667 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Camaioni, Donald M.; Franz, James A.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1607 - 1613
反应条件
perchloric acid; hexaoxo-.mu.-peroxodisulfate(2-); Cu(II) perchlorate in water; acetonitrile T=83°C; 0.416667 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Camaioni, Donald M.; Franz, James A.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1607 - 1613
反应条件
1: S2O8(2-), HClO4 / Cu(ClO4)2 / acetonitrile; H2O / 0.42 h / 83 °C 3: Amberlyst-15 strong acid resin / benzene / Heating 4: H2 / 5percent Pd/C 5: S2O8(2-), HClO4 / Cu(ClO4)2 / acetonitrile; H2O / 0.42 h / 83 °C View Scheme
参考文献
Camaioni, Donald M.; Franz, James A.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1607 - 1613
反应条件
perchloric acid; hexaoxo-.mu.-peroxodisulfate(2-); Cu(II) perchlorate in water; acetonitrile T=83°C; 0.416667 h; other reaction condition; MechanismProduct distribution;
参考文献
Camaioni, Donald M.; Franz, James A.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1607 - 1613
反应条件
Cs/Na/K alloy 1) NH3, -75 deg C, 2 h, 2) H2O; Yield given. Multistep reaction;
参考文献
Sengupta, Dibyendu; Grovenstein, E.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1986 , vol. 25, p. 185 - 186
反应条件
Cs/Na/K alloy multistep reaction: 1.) THF, -75 deg C, 2 h, rate of cleavage relative to bibenzyl; Product distribution;
参考文献
Grovenstein, Erling; Bhatti, Amjad M.; Quest, Dean E.; Sengupta, Dibyendu; VanDerveer, Don
Journal of the American Chemical Society, 1983 , vol. 105, # 20 p. 6290 - 6299
反应条件
hydrogen in 1,2,3,4-tetrahydro-naphthalene T=410°C; P=63755.1 Torr; Ea, ΔH; or at 440 deg C; Rate constantThermodynamic data;
参考文献
Korobkov, V. Yu.; Kalechits, I. V.
Russian Journal of Physical Chemistry, 1991 , vol. 65, # 3 p. 346 - 351
Zhurnal Fizicheskoi Khimii, 1991 , vol. 65, p. 657 - 665
反应条件
perchloric acid; hexaoxo-.mu.-peroxodisulfate(2-); Cu(II) perchlorate in water; acetonitrile T=83°C; 0.416667 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 49, # 9 p. 1607 - 1613
反应条件
perchloric acid; hexaoxo-.mu.-peroxodisulfate(2-); Cu(II) perchlorate in water; acetonitrile T=83°C; 0.416667 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 49, # 9 p. 1607 - 1613