4-溴-N-(二苯亚甲基)苯胺合成路线 （共 14 条）
反应条件
1: thionyl chloride / CCl4 / 5 h / 20 °C
2: ammonium hydroxide / CH2Cl2; H2O / 48 h
3: n-BuLi / tetrahydrofuran; hexane / 1 h / -75 °C
View Scheme
参考文献
Theodorou, Vassiliki; Skobridis, Konstantinos; Karkatsoulis, Aris
Tetrahedron, 2007 , vol. 63, # 20 p. 4284 - 4289
反应条件
1: ammonium hydroxide / CH2Cl2; H2O / 48 h
2: n-BuLi / tetrahydrofuran / 1 h / -75 °C
3: Heating
View Scheme
参考文献
Theodorou, Vassiliki; Skobridis, Konstantinos; Karkatsoulis, Aris
Tetrahedron, 2007 , vol. 63, # 20 p. 4284 - 4289
反应条件
tris(dibenzylideneacetone)dipalladium (0); 18-crown-6 ether; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl; sodium t-butanolate in tetrahydrofuran
48 h; Ambient temperature;
参考文献
Wolfe, John P.; Ahman, Jens; Sadighi, Joseph P.; Singer, Robert A.; Buchwald, Stephen L.
Tetrahedron Letters, 1997 , vol. 38, # 36 p. 6367 - 6370
反应条件
in acetonitrile
T=24.84°C; Thermodynamic data;
参考文献
Zhu, Xiao-Qing; Liu, Qiao-Yun; Chen, Qiang; Mei, Lian-Rui
Journal of Organic Chemistry, 2010 , vol. 75, # 3 p. 789 - 808
