反应条件
potassium hydroxide in ethanol
to a soln. of K2Fe(CO)4, prepd. from Fe(CO)5 and KOH in EtOH, was addeddropwise allyl chloride, mixt. was stirred at room temp. for 1 h; dienewas obtained as 88:12 mixt. of (E)- and (Z)-isomers (GLC data); reaction mixt. was poured into water, extd. with light petroleum, exts.were dried (Na2SO4), concd., residue chromd. on SiO2 (light petroleum),sepn. of the diene and Fe-complex (compared with authentic sample) was performed by careful Kugelrohr distn.;
参考文献
Butsugan, Yasuo; Yamashita, Akihiko; Araki, Shuki
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 103 - 108
