2-碘-3-硝基-苯甲酸合成路线 （共 24 条）
反应条件
1: With sodium hydroxide; mercury(II) diacetate
72 h; Heating;
2: With sodium hydroxide; iodine
16 h; Heating;
参考文献
Wong, See-Mun; Shah, Bhavini; Shah, Priyal; Butt, Ian C.; Woon, Esther C.Y.; Wright, James A.; Thompson, Andrew S.; Upton, Christopher; Threadgill, Michael D.
Tetrahedron Letters, 2002 , vol. 43, # 12 p. 2299 - 2302
反应条件
sulfuric acid; nitric acid
参考文献
Morrison,G.F.; Hooz,J.
Journal of Organic Chemistry, 1970 , vol. 35, # 4 p. 1196 - 1198
反应条件
sulfuric acid; nitric acid
T=135°C; 1 h;
参考文献
Barbasiewicz, Michal; Blocki, Krzysztof; Malinska, Maura; Pawlowski, Robert
Dalton Transactions, 2013 , vol. 42, # 2 p. 355 - 358
反应条件
potassium metabisulfite; nitric acid
Diazotization.nachfolgend Behandeln mit Jod-Kaliumjodid-Loesung;
参考文献
James; Kenner; Stubbings
Journal of the Chemical Society, 1920 , vol. 117, p. 775
反应条件
hydrogenchloride; potassium hydroxide; iodine; potassium iodide; sodium nitrite
Yield given. Multistep reaction;
参考文献
Seno, Kaoru; Hagishita, Sanji; Sato, Tomohiro; Kuriyama, Kaoru
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , p. 2012 - 2022
反应条件
1: 2.) HNO3 / 1.) 1 h, room temperature, 2.) AcOH, 2.5 h, 10 +/- 5 deg C
2: 1.) aq. KOH, 2.) HCl, NaNO2, 3.) KI, I2
View Scheme
参考文献
Seno, Kaoru; Hagishita, Sanji; Sato, Tomohiro; Kuriyama, Kaoru
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , p. 2012 - 2022
反应条件
1: sulfuric acid
2: permanganate; magnesium sulfate / 100 °C
3: sulfuric acid
4: potassium pyrosulfite; fuming nitric acid / <10 / Diazotization.nachfolgend Behandeln mit Jod-Kaliumjodid-Loesung
View Scheme
参考文献
James; Kenner; Stubbings
Journal of the Chemical Society, 1920 , vol. 117, p. 775
反应条件
1: permanganate; magnesium sulfate / 100 °C
2: sulfuric acid
3: potassium pyrosulfite; fuming nitric acid / <10 / Diazotization.nachfolgend Behandeln mit Jod-Kaliumjodid-Loesung
View Scheme
参考文献
James; Kenner; Stubbings
Journal of the Chemical Society, 1920 , vol. 117, p. 775
反应条件
1: sulfuric acid
2: potassium pyrosulfite; fuming nitric acid / <10 / Diazotization.nachfolgend Behandeln mit Jod-Kaliumjodid-Loesung
View Scheme
参考文献
James; Kenner; Stubbings
Journal of the Chemical Society, 1920 , vol. 117, p. 775
反应条件
1: 26 percent
2: 93 percent / H2O2 / acetic acid
3: 92 percent / acetic acid; acetic anhydride
View Scheme
参考文献
Walter, Wolfgang; Krische, Bernd; Adiwidjaja, Gunadi
Liebigs Annalen der Chemie, 1980 , # 1 p. 14 - 27
