2,6-二甲基-5-庚烯腈合成路线 （共 15 条）
反应条件
bei der Oxydation und nachfolgender Verseifung des Reaktionsproduktes;
参考文献
Tiemann
Chemische Berichte, 1900 , vol. 33, p. 2958
Full Text Show Details
Crossley; Perkin
Journal of the Chemical Society, 1898 , vol. 73, p. 33,34
反应条件
1: 67 percent / KOH / ethane-1,2-diol; H2O; ethanol / 18 h / Heating 2: 86 percent / oxalyl chloride, pyridine / benzene / 2 h / Ambient temperature 3: 76 percent / triethyl amine / diethyl ether / 1 h / Ambient temperature 4: 82 percent / diethyl ether / Ambient temperature 5: 38 percent / acetonitrile / Irradiation View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
1: 67 percent / KOH / ethane-1,2-diol; H2O; ethanol / 18 h / Heating 2: 86 percent / oxalyl chloride, pyridine / benzene / 2 h / Ambient temperature 3: 76 percent / triethyl amine / diethyl ether / 1 h / Ambient temperature 4: 82 percent / diethyl ether / Ambient temperature 5: 17 percent / acetonitrile / Irradiation View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
1: 67 percent / KOH / ethane-1,2-diol; H2O; ethanol / 18 h / Heating 2: 86 percent / oxalyl chloride, pyridine / benzene / 2 h / Ambient temperature 3: 76 percent / triethyl amine / diethyl ether / 1 h / Ambient temperature 4: 82 percent / diethyl ether / Ambient temperature 5: 17 percent / acetonitrile / Irradiation View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
1: 67 percent / KOH / ethane-1,2-diol; H2O; ethanol / 18 h / Heating 2: 86 percent / oxalyl chloride, pyridine / benzene / 2 h / Ambient temperature 3: 76 percent / triethyl amine / diethyl ether / 1 h / Ambient temperature 4: 82 percent / diethyl ether / Ambient temperature 5: 17 percent / acetonitrile / Irradiation View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
bei der Oxydation und nachfolgender Verseifung des Reaktionsproduktes;
参考文献
Tiemann
Chemische Berichte, 1900 , vol. 33, p. 2958
Full Text Show Details
Crossley; Perkin
Journal of the Chemical Society, 1898 , vol. 73, p. 33,34
反应条件
1: Na2SO4 / CH2Cl2 / 10 h / Heating
2: 81 percent / ethyl chloroformate / diethyl ether / 1 h / Ambient temperature
View Scheme
参考文献
Xiao, Zejun; Timberlake, Jack W.
Tetrahedron, 1998 , vol. 54, # 42 p. 12715 - 12720
反应条件
in dimethyl sulfoxide
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
1: 42 percent / PBr3, pyridine / diethyl ether
2: 60 percent / dimethylsulfoxide
View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
反应条件
1: LiAlH4 / diethyl ether
2: 42 percent / PBr3, pyridine / diethyl ether
3: 60 percent / dimethylsulfoxide
View Scheme
参考文献
Charlton, James Leslie.; Lai, Hoi Kiong.; Lypka, Gerald Nicholas
Canadian Journal of Chemistry, 1980 , vol. 58, p. 458 - 462
