4,4'-二苯基-2-丁酮合成路线 (共 85 条)
反应条件
air; NAF; rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate T=100°C; 12 h;
参考文献
Huang; Li
Chemical Communications, 2001 , # 22 p. 2348 - 2349
反应条件
[Rh(NCMe)2(cod)][BF4] in 1,4-dioxane; water T=90°C; 20 h;
参考文献
Oi, Shuichi; Honma, Yoshio; Inoue, Yoshio
Organic Letters, 2002 , vol. 4, # 4 p. 667 - 669
反应条件
lithium chloride; palladium dichloride in acetic acid T=25°C; Addition; Michael reaction; 20 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 73, # 9 p. 2149 - 2155
反应条件
1: phenyl-trichloro-silane With potassium carbonate in toluene T=20°C; 2 h; 2: (E)-4-phenyl-3-buten-2-one With water; [Rh(OH)(cycloocta-1,5-diene)]2 in toluene T=120°C; 24 h;
参考文献
Koike, Tooru; Du, Xiaoli; Mori, Atsunori; Osakada, Kohtaro
Synlett, 2002 , # 2 p. 301 - 303
反应条件
water; [Rh(NCMe)2(cod)][BF4] in tetrahydrofuran T=60°C; 2 h;
参考文献
Oi, Shuichi; Moro, Mitsutoshi; Ito, Hisanori; Honma, Yoshio; Miyano, Sotaro; Inoue, Yoshio
Tetrahedron, 2002 , vol. 58, # 1 p. 91 - 97
反应条件
tributyl-amine; trifluoroacetic acid; palladium on activated charcoal in N,N-dimethyl-formamide T=70°C; 15 h;
参考文献
Suen, Yat Fan; Hope, Hakon; Nantz, Michael H.; Haddadin, Makhluf J.; Kurth, Mark J.
Tetrahedron Letters, 2006 , vol. 47, # 45 p. 7893 - 7896
反应条件
lithium chloride; palladium dichloride in acetic acid T=25°C; Addition; Michael reaction; 20 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 73, # 9 p. 2149 - 2155
反应条件
boron trifluoride diethyl etherate in dichloromethane T=-78 - 20°C;
参考文献
Bisaro, Fabrice; Prestat, Guillaume; Vitale, Maxime; Poli, Giovanni
Synlett, 2002 , # 11 p. 1823 - 1826
反应条件
α-cyclohexylcyclohexanemethanamine; 1-(4-hydroxyphenyl)ethanone oxime in water Heck reaction; 8 h; Heating;
参考文献
Journal of Organic Chemistry, , vol. 70, # 11 p. 4360 - 4369
反应条件
[Rh(OH)(cycloocta-1,5-diene)]2; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in 1,4-dioxane; water T=20 - 60°C; 3 h; Inert atmosphere; stereoselective reaction;
参考文献
Panteleev, Jane; Huang, Richard Y.; Lui, Erica K. J.; Lautens, Mark
Organic Letters, 2011 , vol. 13, # 19 p. 5314 - 5317