1-(2-硝基苯基)-萘合成路线 （共 15 条）
反应条件
triphenylphosphine in 1,2-dichloro-benzene T=180°C; 24 h;
参考文献
BASF SE; NISHIMAE, Yuichi; KURA, Hisatoshi; KUNIMOTO, Kazuhiko; YAMAGAMI, Ryuhei; TANAKA, Keita
Patent: WO2012/45736 A1, 2012 ;
Location in patent: Page/Page column 101-102 ;
反应条件
1: triethyl phosphite / 24 h / 150 °C 2: N-bromosuccinmide / N,N-dimethyl-formamide / 24 h / 0 °C View Scheme
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; AHN, Hee-choon; YOON, Seok-keun; KIM, Nam-kyun; KIM, Seung-ae; KU, Jong-seok; KWON, Hyuck-joo; LEE, Kyung-joo; KIM, Bong-ok
Patent: WO2013/73874 A1, 2013 ;
反应条件
1: H2, aq. HClO4 / Pd-C 2: (i) BCl3, (ii) AlCl3 View Scheme
参考文献
Bergmann,E.D. et al.
Journal of Organic Chemistry, 1964 , vol. 29, p. 3092 - 3093
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether
T=100°C; 12 h;
参考文献
Shahripour, Aurash B; Plummer, Mark S; Lunney, Elizabeth A; Albrecht, Hans P; Hays, Sheryl J; Kostlan, Catherine R; Sawyer, Tomi K; Walker, Nigel P.C; Brady, Kenneth D; Allen, Hamish J; Talanian, Robert V; Wong, Winnie W; Humblet, Christine
Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 1 p. 31 - 40
反应条件
bis(acetylacetonato) palladium; copper(l) iodide; 1,10-phenanthroline in 1-methyl-pyrrolidin-2-one; quinoline
T=50 - 190°C; P=4125.41 Torr; 0.25 h; Inert atmosphereMicrowave irradiation;
参考文献
Goossen, Lukas J.; Linder, Bettina Zimmermanns Christophe; Rodriguez, Nuria; Lange, Paul P.; Hartung, Jens
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 16 p. 2667 - 2674
反应条件
1: ortho-nitrobenzoic acid With potassium carbonate in various solvent(s)
T=120°C; 0.5 h;
2: 1-Bromonaphthalene With 1,10-phenanthroline; copper(l) iodide in various solvent(s)
T=160°C; 24 h; Further stages.;
参考文献
Goossen, Lukas J.; Rodriguez, Nuria; Melzer, Bettina; Linder, Christophe; Deng, Guojun; Levy, Laura M.
Journal of the American Chemical Society, 2007 , vol. 129, # 15 p. 4824 - 4833
反应条件
sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide
T=150°C; Suzuki-Miyaura cross-coupling reaction; 0.25 h; microwave irradiation;
参考文献
Appukkuttan, Prasad; Van Der Eycken, Erik; Dehaen, Wim
Synlett, 2005 , # 1 art. no. G33904ST, p. 127 - 133
反应条件
copper(I) oxide; 3,4,7,8-tetra-methyl-1,10-phenanthroline; 2-(2-(dicyclohexylphosphino)phenyl)-5,6-dimethyl-1-octyl-1H-benzo[d]imidazole; bis(dibenzylideneacetone)-palladium(0) in 1-methyl-pyrrolidin-2-one; 1,3,5-trimethyl-benzene
T=50 - 180°C; P=1500.15 Torr; 0.583333 h; Inert atmosphereMicrowave irradiation;
参考文献
Song, Bingrui; Knauber, Thomas; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 10 p. 2954 - 2958
Angew. Chem., 2013 , vol. 125, # 10 p. 3026 - 3030
反应条件
tetrabutylammomium bromide; N-ethyl-N,N-diisopropylamine; palladium diacetate in xylene
T=130°C; 74 h;
参考文献
Hassan, Jwanro; Hathroubi, Chokri; Gozzi, Christel; Lemaire, Marc
Tetrahedron, 2001 , vol. 57, # 37 p. 7845 - 7855
反应条件
copper
T=240 - 250°C;
参考文献
Forrest; Tucker
Journal of the Chemical Society, 1948 , p. 1137,1140
