in neat (no solvent)
heating FeC2O4*2H2O in stream of N2 at 200°C, treatment with mixt. of C5H6 and CO at 380°C;;
参考文献
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.1.1, page 15 - 16
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Holzapfel, H.; Huebner, H.; Geissler, C.; Rolle, W.
Patent: DE43979 , 1965 ;
C. A., 1966 , vol. 64, p. 17642
in not given
addn. of C5H6 to Fe(2+) halogenide at ambient temp. and presence of high excess of NaOCH3;;
参考文献
Cordes, H.
Angewandte Chemie, 1965 , vol. 77, p. 1017 - 1017
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Cordes, H.
Zeitschrift fuer Naturforschung, 1966 , vol. 21 b, p. 746 - 751
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Gmelin Handbook: Fe: Org.Verb.A1, 2.1.1.2, page 16 - 18
in not given
addn. of C5H6 to Fe(2+) halogenide at ambient temp. and presence of high excess of NaOC2H5;;
参考文献
Cordes, H.
Angewandte Chemie, 1965 , vol. 77, p. 1017 - 1017
Full Text Show Details
Cordes, H.
Zeitschrift fuer Naturforschung, 1966 , vol. 21 b, p. 746 - 751
Full Text Show Details
Gmelin Handbook: Fe: Org.Verb.A1, 2.1.1.2, page 16 - 18
in neat (no solvent)
Iron atoms were codeposited with benzene-hexane at -196°C over 30 min, the mixt. was warmed to -78°C and cyclopentadiene was distilled into the reactor, the mixt. was stirred for 1 h at this temp. thenslowly warmed to room temp.;; evapd., sublimed,;
参考文献
Beard, Loren K.; Silvon, Michael P.; Skell, Philip S.
Journal of Organometallic Chemistry, 1981 , vol. 209, # 2 p. 245 - 254
in neat (no solvent)
Iron atoms were codeposited with toluene at -196°C over 30 min, the mixt. was warmed to -78°C and cyclopentadiene was distilled into the reactor, the mixt. was warmed to room temp.;; filtered, evapd., ferrocene was removed by fractional sublimation, three isomers were inseparable;;
参考文献
Beard, Loren K.; Silvon, Michael P.; Skell, Philip S.
Journal of Organometallic Chemistry, 1981 , vol. 209, # 2 p. 245 - 254
in diethylamine
addn. of C5H6 to Fe(2+) halogenide at ambient temp. and presence of high excess of NH(C2H5)2;;
参考文献
Gelius, R.; Uhlmann, W.; Sperling, W.
Z. Chem. (Leipzig), 1966 , vol. 6, p. 227 - 228
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Gmelin Handbook: Fe: Org.Verb.A1, 2.1.1.2, page 16 - 18
in neat (no solvent)
Iron atoms were codeposited with toluene at -196°C over 30 min, the mixt. was warmed to -78°C and m-xylene was distilled, stirredfor 24 h, cyclopentadiene was distilled in, the mixt. was warmed to room temp. over 1 h;; evapd., ppt. was dissolved in pentane, filtered, evapd.;;
参考文献
Beard, Loren K.; Silvon, Michael P.; Skell, Philip S.
Journal of Organometallic Chemistry, 1981 , vol. 209, # 2 p. 245 - 254
Ohara,M. et al.
Tetrahedron Letters, 1968 , p. 3489 - 3490
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Okada, T.; Okawara, R.
J, Organometal. Chem., 1972 , vol. 42, p. 117 - 121
