5-羟基-2,2-二甲基-2H-色烯-6-甲醛合成路线 （共 11 条）
反应条件
pyridine in acetone T=20 - 120°C; 24 h; Inert atmosphere;
参考文献
Shi, Zhuangzhi; Schroeder, Nils; Glorius, Frank
Angewandte Chemie - International Edition, 2012 , vol. 51, # 32 p. 8092 - 8096
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone in diethyl ether Ambient temperature;
参考文献
Nomura, Taro; Fukai, Toshio; Hano, Yoshio; Tsukamoto, Koji
Heterocycles, 1983 , vol. 20, # 4 p. 661 - 666
反应条件
in m-xylene T=180°C; 0.5 h; Microwave irradiationInert atmosphere;
参考文献
Garcia, Jose; Barluenga, Sofia; Beebe, Kristin; Neckers, Len; Winssinger, Nicolas
Chemistry - A European Journal, 2010 , vol. 16, # 32 p. 9767 - 9771
反应条件
1.1: 99 percent / TsOH*H2O / tetrahydrofuran; methanol / 1 h / 25 °C 2.1: polystyrene-based selenenyl bromide resin / CH2Cl2 / 0.33 h / 0 - 25 °C 2.2: H2O2 / tetrahydrofuran / 0.33 h / 25 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 122, # 41 p. 9939 - 9953
反应条件
in pyridine 40 h; Heating;
参考文献
Mohamed, Salah E. N.; Thomas, Philip; Whiting, Donald A.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 431 - 438
反应条件
pyridine 0.416667 h; Irradiationmicrowave irradiation;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 72, # 2 p. 259 - 263
反应条件
1: 540 mg / BF3*Et2O / dioxane / 2 h / Ambient temperature 2: 160 mg / 2,3-dicyano-5,6-dichloro-p-benzoquinone (DDQ) / diethyl ether / Ambient temperature View Scheme
参考文献
Heterocycles, , vol. 20, # 4 p. 661 - 666
反应条件
1: 540 mg / BF3*Et2O / dioxane / 2 h / Ambient temperature 2: 160 mg / 2,3-dicyano-5,6-dichloro-p-benzoquinone (DDQ) / diethyl ether / Ambient temperature View Scheme
参考文献
Heterocycles, , vol. 20, # 4 p. 661 - 666
反应条件
C5H2Ph4; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; copper diacetate in 1,2-dichloro-ethane T=120°C; Mizoroki-Heck reaction; 18 h; Inert atmosphere; regioselective reaction;
参考文献
Shi, Zhuangzhi; Schroeder, Nils; Glorius, Frank
Angewandte Chemie - International Edition, 2012 , vol. 51, # 32 p. 8092 - 8096
反应条件
in xylene
10 h; Heating;
参考文献
Lee, Yong Rok; Lee, Won Kyong; Noh, Seok Kyun; Lyoo, Won Seok
Synthesis, 2006 , # 5 p. 853 - 859
