反应条件
in sodium hydroxide Electrochem. Process; open vessel, Pt cathode/Ti anode; electrolyte: NaOH/Ba(CH3COO)2 (0.5M, pH 12.25; preheating NaOH, addn. of Ba(2+) salt); current: 0.5mA/cm**2, at 100°C, 48h, N2 reflux; prior to anode deposition purging soln. for 24h with N2; mechanism discussed;; detn. by XRD, AES; formation of TiO/TiO2 as dominant phases and BaCO3 close to surface;;
参考文献
Journal of the American Ceramic Society, , vol. 76, # 10 p. 2619 - 2627
