oxygen; copper(l) chloride in pyridine 6 h;

1: With hydrogenchloride; sodium nitrite in water T=0°C; 1 h; 2: With ammonium hydroxide; CuSO4‵5H2O; hydroxylamine hydrochloride; sodium hydroxide in water T=70°C; 1 h;

hydrogenchloride; ammonia; sodium nitrite in 6N-sodium hydroxide; water

hydrogenchloride; sodium hydroxide; sodium hydrogencarbonate; sodium nitrite in water; acetic anhydride

bromine T=200°C;

暂无反应条件数据

1: 49 percent / HCl(gas) / 48 h / Ambient temperature 2: 90 percent / LiAlH4 / diethyl ether / 48 h / Ambient temperature 3: 79 percent / 33percent HBr/HOAc / 18 h / 80 °C View Scheme

1: 49 percent / HCl(gas) / 48 h / Ambient temperature 2: 90 percent / LiAlH4 / diethyl ether / 48 h / Ambient temperature 3: 79 percent / 33percent HBr/HOAc / 18 h / 80 °C 4: 97 percent / LiAlH4 / tetrahydrofuran / 20 h / Ambient temperature 5: 1.) n-butyllithium / 1.) petroleum ether, hexane, reflux, 20 h, 2.) petroleum ether, haxane, reflux, 22 h View Scheme

methyllithium; calcium carbonate