Baroni, A.; Marini Bettolo, G. B.
Gazzetta Chimica Italiana, 1942 , vol. 72, p. 22 - 27
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Gmelin Handbook: Cu: MVol.B1, 50, page 102 - 105
→
反应条件
in neat (no solvent, solid phase) stirring of AlH3-Cu(HCOO)2-Mg at ratio of Al-Cu-Mg of 54.2:9.2:36.6 (atpercent) in inert atmosphere, heating at 650°C in vac. for 1 h; monitoring by XRD;
参考文献
Aldoshin; Dzhardimalieva; Pomogailo; Abuzin
Russian Chemical Bulletin, 2011 , vol. 60, # 9 p. 1871 - 1879
ammonia; ascorbic acid powder in water
byproducts: dehydroascorbic acid; soln. of L-ascorbic acid neutralized to pH 5.5-6.5 by NaOH or KOH, heated to 30-35°C, added dropwize to soln. of Cu-salt with stirring, complexig agent ammonia; Cu-powder formed in 3-20 min; washed (H2O) to neutral rect., treated with soln. of hydroquinone and stearic acid in EtOH; detd. by X-ray phase anal.;
参考文献
Gmelin Handbook: Cu: MVol.A1, 5.1.1.1, page 488 - 490
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Ipatiew, W.; Ipatiew, W.
Ber., 1927 , vol. 60, p. 1982 - 1986
