2,7-二溴-9-(2-乙基己基)-9h-咔唑合成路线 （共 7 条）
反应条件
1: 2,7-dibromo-9-H-carbazole With sodium hydride in N,N-dimethyl-formamide
0.5 h;
2: 2-ethyl-hexyl-1-bromide in N,N-dimethyl-formamide
18 h;
参考文献
Dierschke, Frank; Grimsdale, Andrew C.; Muellen, Klaus
Synthesis, 2003 , # 16 p. 2470 - 2472
反应条件
p-methylnitrobenzene
T=160°C; 5 h; Inert atmosphere;
参考文献
Vyprachticky, Drahomir; Kminek, Ivan; Pokorna, Veronika; Cimrova, Vera
Tetrahedron, 2012 , vol. 68, # 25 p. 5075 - 5080
反应条件
sodium hydroxide in acetone
参考文献
National University Of Singapore
Patent: US2007/290199 A1, 2007 ;
反应条件
1.1: 91 percent / aq. HNO3 / acetic acid / 0.5 h / 100 °C
2.1: 56 percent / triethyl phosphite / 18 h / Heating
3.1: NaH / dimethylformamide / 0.5 h
3.2: 96 percent / dimethylformamide / 18 h
View Scheme
参考文献
Dierschke, Frank; Grimsdale, Andrew C.; Muellen, Klaus
Synthesis, 2003 , # 16 p. 2470 - 2472
反应条件
1.1: 56 percent / triethyl phosphite / 18 h / Heating
2.1: NaH / dimethylformamide / 0.5 h
2.2: 96 percent / dimethylformamide / 18 h
View Scheme
参考文献
Dierschke, Frank; Grimsdale, Andrew C.; Muellen, Klaus
Synthesis, 2003 , # 16 p. 2470 - 2472
反应条件
1: 90 percent / SnCl2 / ethanol / 2 h / 70 °C
2: 80 percent / H3PO4 / 40 h / 200 °C
3: 58 percent / K2CO3 / dimethylformamide / 24 h / 70 °C
View Scheme
参考文献
Wang, Hui; Ryu, Jeong-Tak; Han, Yoon Soo; Kim, Dae-Hwan; Choi, Byeong Dae; Park, Lee Soon; Kwon, Younghwan
Molecular Crystals and Liquid Crystals, 2006 , vol. 459, # 1 p. 85/[365]-94/[374]
反应条件
1: 80 percent / H3PO4 / 40 h / 200 °C
2: 58 percent / K2CO3 / dimethylformamide / 24 h / 70 °C
View Scheme
参考文献
Wang, Hui; Ryu, Jeong-Tak; Han, Yoon Soo; Kim, Dae-Hwan; Choi, Byeong Dae; Park, Lee Soon; Kwon, Younghwan
Molecular Crystals and Liquid Crystals, 2006 , vol. 459, # 1 p. 85/[365]-94/[374]
