54509-73-8合成路线 （共 3623 条）
反应条件
(i) Cl2, (ii) H2S, (iii) aq. NaOH; Multistep reaction;
参考文献
Beger,J. et al.
Journal fuer Praktische Chemie (Leipzig), 1969 , vol. 311, p. 408 - 419
反应条件
1: β-naphthol With (S)-dtbm-segphos; [Ir(cyclooctene)Cl]2 in 1,3,5-trimethyl-benzene T=140°C; 24 h; Inert atmosphereSchlenk technique; 2: ethene
参考文献
Sevov, Christo S.; Hartwig, John F.
Journal of the American Chemical Society, 2013 , vol. 135, # 25 p. 9303 - 9306
反应条件
T=280°C; P=100 Torr;
参考文献
Reeve; Adkins
Journal of the American Chemical Society, 1940 , vol. 62, p. 2874
反应条件
Ki in sulfolane; water
反应条件
N-bromosuccinmide; water; potassium hydrogencarbonate T=60°C; P=25858.1 Torr; 4 h; Product distribution / selectivity;
参考文献
WO2008/34265 A1, ;
Page/Page column 19 ;
→
17741-60-53,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757574 A1, 2007 ;
Location in patent: Page/Page column 9 ;
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757574 A1, 2007 ;
Location in patent: Page/Page column 8-9 ;
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757574 A1, 2007 ;
Location in patent: Page/Page column 9-10 ;
反应条件
(SPY-5-31)-dichloro-(κ2(C,O)-(2-isopropyloxybenzylidene))(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)ruthenium; [(t-Bu3P)PdBr]2 in tetrahydrofuran T=60°C; P=7500.75 Torr; 16 h; Autoclave; TimePressureConcentration;
参考文献
Baader, Sabrina; Ohlmann, Dominik M.; Goossen, Lukas J.
Chemistry - A European Journal, 2013 , vol. 19, # 30 p. 9807 - 9810
反应条件
(SPY-5-31)-dichloro-(κ2(C,O)-(2-isopropyloxybenzylidene))(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)ruthenium in tetrahydrofuran T=60°C; P=7500.75 Torr; 16 h; Autoclave; Reagent/catalystSolvent;
参考文献
Baader, Sabrina; Ohlmann, Dominik M.; Goossen, Lukas J.
Chemistry - A European Journal, 2013 , vol. 19, # 30 p. 9807 - 9810
