54509-73-8合成路线 （共 3623 条）
反应条件
CO in hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;
参考文献
Kampe, C. E.; Boag, N. M.; Kaesz, H. D.
Journal of Molecular Catalysis, 1983 , vol. 21, p. 297 - 312
反应条件
in benzene N2; reaction in a Carius tube; 85 ° C for 24 h;; the solution was cooled and the excess of ethene vented; solvent removal; the residue was purified by thin layer chromy. (petroleum ether /acetone);;
参考文献
Journal of Organometallic Chemistry, , vol. 445, # 1.2 p. 187 - 198
反应条件
Ph3P(+)CH3I(-); triphenylphosphine; ruthenium trichloride in various solvent(s) T=180°C; P=60004.8 Torr; 4 h; Further byproducts given;
参考文献
Tetrahedron Letters, , vol. 32, # 32 p. 3989 - 3992
反应条件
Ph3P(+)CH3I(-); triphenylphosphine; Rhodium trichloride in various solvent(s) T=180°C; P=60004.8 Torr; 4 h; further ereaction conditions and promotors; Product distribution;
参考文献
Tetrahedron Letters, , vol. 32, # 32 p. 3989 - 3992
反应条件
copper in water Kinetics; other Radiation; pulse irradiation of mixt. of Cu(II)-salt (sulphate or perchlorate, not specified) and olefin ((60)Co-γ-rays, 2-5 krad/min, Ar-atmosphere), then treatment with oxygenated water; not isolated, reaction followed by stopped-flow UV/VIS spectroscopy;
参考文献
Buxton, George V.; Green, John C.; Sellers, Robin M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976 , p. 2160 - 2165
参考文献
US2011/87038 A1, ;
Page/Page column 6-7 ;
反应条件
T=280°C; P=97822.5 Torr;
参考文献
Journal of the American Chemical Society, , vol. 62, p. 2847
反应条件
HY (CBV600, Si/Al = 2.6) zeolite T=219.84°C; P=35178.5 Torr; 6 h; Reagent/catalyst;
参考文献
MICROMIDAS INC.; MICHIGAN MOLECULAR INSTITUTE; MASUNO, Makoto, N.; CANNON, Douglas; BISSELL, John; SMITH, Ryan, L.; FOSTER, Marc; WOOD, Alex, Benjamin; SMITH, Patrick, B.; HUCUL, Dennis A.
Patent: WO2013/40514 A1, 2013 ;
Location in patent: Paragraph 0125; 0126 ;
反应条件
C28H37IrP2 T=20 - 250°C; Diels-Alder Cycloaddition; P=31029.7 Torr; 24.5 h; Inert atmosphereGlovebox;
参考文献
Lyons, Thomas W.; Guironnet, Damien; Findlater, Michael; Brookhart, Maurice
Journal of the American Chemical Society, 2012 , vol. 134, # 38 p. 15708 - 15711,4
Title/Abstract Full Text Show Details
Lyons, Thomas W.; Guironnet, Damien; Findlater, Michael; Brookhart, Maurice
Journal of the American Chemical Society, 2012 , vol. 134, # 38 p. 15708 - 15711
反应条件
carbon T=150°C; P=26618.1 Torr; 24 h; Sealed; Product distribution / selectivity;
参考文献
BRANDVOLD, Timothy A.
Patent: US2010/331568 A1, 2010 ;
Location in patent: Page/Page column 4 ;
