54509-73-8合成路线 （共 3623 条）
反应条件
1: With [(t-Bu)NP(Ph)2N(t-Bu)]Cr(μ2-Cl)2Li(THF)2 in toluene T=100°C; P=26252.6 Torr; 1 h; Inert atmosphere; 2: With hydrogenchloride in ethanol; toluene
参考文献
Organometallics, , vol. 30, # 12 p. 3346 - 3352
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine; potassium tert-butylate 1.) hexane, -25 deg C, 2 h, 2.) THF, -30 deg C; Yield given. Multistep reaction;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 3 p. 260 - 261
反应条件
tetramethylstannane; [MoCl5]; silica gel T=27°C; Kinetics; Further Variations:Temperatures;
参考文献
Petroleum Chemistry, , vol. 45, # 6 p. 429 - 432
反应条件
aluminum tri-bromide; hydrogen bromide T=-78°C;
参考文献
Shell Devel.Co.
Patent: US2672439 , 1950 ;
Full Text Show Details
N.V. de Bataafsche Petr.Mij.
Patent: DE846692 , 1950 ;
DRP/DRBP Org.Chem.
参考文献
Berthelot
Justus Liebigs Annalen der Chemie, 1857 , vol. 104, p. 184
Full Text Show Details
Berthelot
Justus Liebigs Annalen der Chemie, 1860 , vol. 115, p. 114
参考文献
Rust; Vaughan
Journal of Organic Chemistry, 1942 , vol. 7, p. 495
反应条件
in pentane (Ar); Fe compd. was reacted with C2H4 under pressure of 750 psi with stirring for 2 d at room temp.; fractional distn. gave first Fe(CO)5, then desired product;
参考文献
Beach, David B.; Jolly, William L.
Inorganic Chemistry, 1983 , vol. 22, p. 2137 - 2139
反应条件
in further solvent(s) Irradiation (UV/VIS); >540nm, C2H4-satd. CF3C6H11-soln, 298K; monitoring of react. by (1)H-NMR;; detn. by IR, UV, (1)H-NMR; molar ratio of Fe(CO)4(C2H4) and Fe(CO)3(C2H4)2=1:1;;
参考文献
Bentsen, James G.; Wrighton, Mark S.
Journal of the American Chemical Society, 1987 , vol. 109, # 15 p. 4530 - 4544
反应条件
in further solvent(s) Irradiation (UV/VIS); >540nm, C2H4-satd. 3-methylpentane soln., 195K;; detn. by IR;;
参考文献
Bentsen, James G.; Wrighton, Mark S.
Journal of the American Chemical Society, 1987 , vol. 109, # 15 p. 4530 - 4544
反应条件
in 1,4-dioxane byproducts: cyclopentadiene, propene, hydrocarbons; Complex in p-dioxane was charged with C2H4 (450 psi) and heated at 160°C for 10 h;; not sepd., detected by IR spectra and GC and GC-MS analysis;;
参考文献
Kao, S. C.; Lu, Paul P. Y.; Pettit, R.
Organometallics, 1982 , vol. 1, p. 911 - 918
