54509-73-8合成路线 （共 3623 条）
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757574 A1, 2007 ;
Location in patent: Page/Page column 8-9 ;
反应条件
in methanol; xylene byproducts: Et3SiCl; Ar-atmosphere; mixing BCl3, Et3SiH and C2H4, distillation of EtBCl2, addn. of MeOH; collection (distillation); NMR spectroscopy;
参考文献
Soundararajan, Raman; Matteson, Donald S.
Organometallics, 1995 , vol. 14, p. 4157 - 4166
反应条件
bis(1,5-cyclooctadiene)nickel (0); tri-cyclo-hexyl-phosphine 1.) THF, -78 to -10 deg C, 20 h, 2.) THF, 20 deg C, 1 bar, 2 h; Yield given. Multistep reaction;
参考文献
Hoberg, Heinz; Suemmermann, Klaus; Milchereit, Armin
Journal of Organometallic Chemistry, 1985 , vol. 288, p. 237 - 248
反应条件
1.) THF, -78 to 20 deg C, 1 bar, 17 h, 2.) THF, 20 deg C, 1 bar, 2 h; Yield given. Multistep reaction;
参考文献
Hoberg, Heinz; Suemmermann, Klaus; Milchereit, Armin
Journal of Organometallic Chemistry, 1985 , vol. 288, p. 237 - 248
反应条件
B(C6F5)3 in methanol
参考文献
Wang, Lin; Arthur, Samuel David; McCord, Elizabeth Forrester; Wang, Yueli; Morken, Peter Arnold; Johnson, Lynda Kaye
Patent: US2003/212225 A1, 2003 ;
参考文献
DE529524 , ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 17, p. 115
Angewandte Chemie, , vol. 43, p. 234,236
Chem. Zentralbl., , vol. 101, # I p. 3170
反应条件
T=200°C; beim Leiten durch ein Rohr;
参考文献
Chem. Zentralbl., , vol. 109, # I p. 3387
US2099231 , ;
反应条件
TBA p-toluenesulfonate; chlorine in dichloromethane T=20°C; 0.25 h;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 20, p. 205 - 213
Zhurnal Organicheskoi Khimii, , vol. 20, # 2 p. 233 - 242
反应条件
hydrogenchloride in water; acetonitrile T=5 - 10°C; P=45003.6 Torr; electrolysis, further solvent methanol;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 32, # 3 p. 523 - 525
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 3 p. 582 - 584
反应条件
hydrogenchloride in methanol T=5 - 10°C; P=45003.6 Torr; electrolysis, further solvent aq. acetonitrile;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 32, # 3 p. 523 - 525
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 3 p. 582 - 584
