乙基[(1S)-1-乙炔基-2,3-二羟基环戊基]乙酸酯合成路线 （共 5 条）
反应条件
osmium(VIII) oxide; 4-methylmorpholine N-oxide in water; acetone; tert-butyl alcohol
T=0 - 20°C; 1.33333 h;
参考文献
Sumi, Shinjiro; Matsumoto, Koji; Tokuyama, Hidetoshi; Fukuyama, Tohru
Tetrahedron, 2003 , vol. 59, # 43 p. 8571 - 8587
反应条件
1: pivalic acid / xylene / 10 h / Heating
2: tetra-n-butylammonium fluoride / tetrahydrofuran / 0.75 h / 50 °C
3: 2.10 g / N-methylmorpholine N-oxide; OsO4 / H2O; 2-methyl-propan-2-ol; acetone / 1.33 h / 20 °C
View Scheme
参考文献
Sumi, Shinjiro; Matsumoto, Koji; Tokuyama, Hidetoshi; Fukuyama, Tohru
Organic Letters, 2003 , vol. 5, # 11 p. 1891 - 1893
反应条件
1: tetra-n-butylammonium fluoride / tetrahydrofuran / 0.75 h / 50 °C
2: 2.10 g / N-methylmorpholine N-oxide; OsO4 / H2O; 2-methyl-propan-2-ol; acetone / 1.33 h / 20 °C
View Scheme
参考文献
Sumi, Shinjiro; Matsumoto, Koji; Tokuyama, Hidetoshi; Fukuyama, Tohru
Organic Letters, 2003 , vol. 5, # 11 p. 1891 - 1893
反应条件
1: pivalic acid / xylene / Heating
2: tetra-n-butylammonium fluoride / tetrahydrofuran / 0.75 h / 50 °C
3: N-methylmorpholine N-oxide; osmium tetroxide / acetone; H2O; 2-methyl-propan-2-ol / 1.33 h / 0 - 20 °C
View Scheme
参考文献
Sumi, Shinjiro; Matsumoto, Koji; Tokuyama, Hidetoshi; Fukuyama, Tohru
Tetrahedron, 2003 , vol. 59, # 43 p. 8571 - 8587
反应条件
1: pivalic acid / xylene / Heating
2: tetra-n-butylammonium fluoride / tetrahydrofuran / 0.75 h / 50 °C
3: N-methylmorpholine N-oxide; osmium tetroxide / acetone; H2O; 2-methyl-propan-2-ol / 1.33 h / 0 - 20 °C
View Scheme
参考文献
Sumi, Shinjiro; Matsumoto, Koji; Tokuyama, Hidetoshi; Fukuyama, Tohru
Tetrahedron, 2003 , vol. 59, # 43 p. 8571 - 8587
