1,1,1,3,5,5,5-七甲基-3-苯基三硅氧烷合成路线 （共 14 条）
反应条件
potassium acetate; bis(dibenzylideneacetone)-palladium(0) in 1-methyl-pyrrolidin-2-one T=20°C; 16 h;
参考文献
Murata, Miki; Ota, Kosuke; Yamasaki, Hiroyuki; Watanabe, Shinji; Masuda, Yuzuru
Synlett, 2007 , # 9 p. 1387 - 1390
反应条件
1: 1-phenyl-1-chlorotetramethyldisiloxane With lithium in tetrahydrofuran T=-78°C; Metallation; self-condensation; 2 h; 2: dimethylmono-chlorosilane in tetrahydrofuran T=20°C; Substitution; 24 h;
参考文献
Harloff, Joerg; Popowski, Eckhard; Fuhrmann, Hans
Journal of Organometallic Chemistry, 1999 , vol. 592, # 1 p. 136 - 146
反应条件
KOH in potassium hydroxide aq. KOH; at 60°C;;
参考文献
Journal of the American Chemical Society, , vol. 70, p. 1115 - 1117
Si: MVol.C, 106, page 292 - 295
反应条件
water in toluene T=20°C; 27 h;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 61, # 6.2 p. 1378 - 1383,1257 - 1261
反应条件
water Erhitzen des Reaktionsprodukts unter vermindertem Druck und Erwaermen des danach isolierten Reaktionsprodukts mit Hexamethyl-disiloxan in Isopropylalkohol und Toluol und mit wss. Kalilauge;
参考文献
Journal of the American Chemical Society, , vol. 70, p. 1115,1116
反应条件
potassium hydrotris(3,5-dimethylpyrazolyl)borate; platinum (II) chloride T=150°C; Hiyama cross-coupling; 24 h;
参考文献
Murata, Miki; Fukuyama, Naoaki; Wada, Jun-Ichi; Watanabe, Shinji; Masuda, Yuzuru
Chemistry Letters, 2007 , vol. 36, # 7 p. 910 - 911
反应条件
lithium in tetrahydrofuran T=-78°C; Substitution; 2 h; Further byproducts given;
参考文献
Journal of Organometallic Chemistry, , vol. 592, # 1 p. 136 - 146
反应条件
potassium hydrotris(3,5-dimethylpyrazolyl)borate; platinum (II) chloride T=200°C; Hiyama cross-coupling; 24 h; Title compound not separated from byproducts.;
参考文献
Chemistry Letters, , vol. 36, # 7 p. 910 - 911
参考文献
Zhurnal Obshchei Khimii, , vol. 29, p. 1534,1536,1539; engl.Ausg.S.1508,1509,1511
反应条件
T=20°C; Further byproducts given;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, # 5 p. 1082 - 1084
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 36, # 5 p. 1169 - 1171
