hydrogenchloride; hydrogen; rhenium heptasulfide in methanol T=25°C; 45 h;

1: 95 percent / NaSCH2Ph / CH2Cl2 / 4 h / Ambient temperature 2: 99 percent / NaN3, aliquat 336 / H2O / 7 h / 45 °C 3: 63 percent / H2, HCl / Re2S7 / methanol / 45 h / 25 °C View Scheme

1: CaCO3 / CH2Cl2 / 4 h / 25 °C 2: 99 percent / NaN3, aliquat 336 / H2O / 7 h / 45 °C 3: 63 percent / H2, HCl / Re2S7 / methanol / 45 h / 25 °C View Scheme

1: 99 percent / NaN3, aliquat 336 / H2O / 7 h / 45 °C 2: 63 percent / H2, HCl / Re2S7 / methanol / 45 h / 25 °C View Scheme