甲基-alpha-L-葡糖胺合成路线 （共 30 条）
反应条件
2: 51 percent / pyridine / refrigerator, overnight 3: 87 percent / AG 1-X4(OH-) / methanol / 2 h / Ambient temperature 4: 81 percent / NaN3, NH4Cl / 2-methoxy-ethanol; H2O / 2 h / 100 °C 5: H2 / 10percent Pd/C / methanol / 15 h / 2280 Torr View Scheme
参考文献
Journal of Organic Chemistry, , vol. 48, # 26 p. 5309 - 5315
反应条件
1: AG 50-X4(H+) / methanol / Ambient temperature 2: NIS, P(C6H5)3 / dimethylformamide / 1 h / 50 °C 3: H2 / Ra-Ni / methanol / Heating 4: 51 percent / pyridine / refrigerator, overnight 5: 87 percent / AG 1-X4(OH-) / methanol / 2 h / Ambient temperature 6: 81 percent / NaN3, NH4Cl / 2-methoxy-ethanol; H2O / 2 h / 100 °C 7: H2 / 10percent Pd/C / methanol / 15 h / 2280 Torr View Scheme
参考文献
Journal of Organic Chemistry, , vol. 48, # 26 p. 5309 - 5315
反应条件
1: NIS, P(C6H5)3 / dimethylformamide / 1 h / 50 °C 2: H2 / Ra-Ni / methanol / Heating 3: 51 percent / pyridine / refrigerator, overnight 4: 87 percent / AG 1-X4(OH-) / methanol / 2 h / Ambient temperature 5: 81 percent / NaN3, NH4Cl / 2-methoxy-ethanol; H2O / 2 h / 100 °C 6: H2 / 10percent Pd/C / methanol / 15 h / 2280 Torr View Scheme
参考文献
Journal of Organic Chemistry, , vol. 48, # 26 p. 5309 - 5315
反应条件
1: 54 percent / aq. sodium carbonate / tetrahydrofuran 2: diisobutylaluminum hydride 3: Amberlite CG 120 resin (H+ form) 4: 75 percent / sodium, liq. ammonia 5: H2O, OH- View Scheme
参考文献
Journal of the American Chemical Society, , vol. 103, # 13 p. 3956 - 3958
反应条件
1: xylene / Heating 2: 40 percent / xylene / Heating 3: 89 percent / Zn, aq. acetic acid 4: 54 percent / aq. sodium carbonate / tetrahydrofuran 5: diisobutylaluminum hydride 6: Amberlite CG 120 resin (H+ form) 7: 75 percent / sodium, liq. ammonia 8: H2O, OH- View Scheme
参考文献
Journal of the American Chemical Society, , vol. 103, # 13 p. 3956 - 3958
反应条件
1: 89 percent / Zn, aq. acetic acid 2: 54 percent / aq. sodium carbonate / tetrahydrofuran 3: diisobutylaluminum hydride 4: Amberlite CG 120 resin (H+ form) 5: 75 percent / sodium, liq. ammonia 6: H2O, OH- View Scheme
参考文献
Journal of the American Chemical Society, , vol. 103, # 13 p. 3956 - 3958
反应条件
1: 40 percent / xylene / Heating 2: 89 percent / Zn, aq. acetic acid 3: 54 percent / aq. sodium carbonate / tetrahydrofuran 4: diisobutylaluminum hydride 5: Amberlite CG 120 resin (H+ form) 6: 75 percent / sodium, liq. ammonia 7: H2O, OH- View Scheme
参考文献
Journal of the American Chemical Society, , vol. 103, # 13 p. 3956 - 3958
反应条件
1: 81 percent / NaN3, NH4Cl / 2-methoxy-ethanol; H2O / 2 h / 100 °C 2: H2 / 10percent Pd/C / methanol / 15 h / 2280 Torr View Scheme
参考文献
Journal of Organic Chemistry, , vol. 48, # 26 p. 5309 - 5315
反应条件
1: 51 percent / pyridine / refrigerator, overnight 2: 87 percent / AG 1-X4(OH-) / methanol / 2 h / Ambient temperature 3: 81 percent / NaN3, NH4Cl / 2-methoxy-ethanol; H2O / 2 h / 100 °C 4: H2 / 10percent Pd/C / methanol / 15 h / 2280 Torr View Scheme
参考文献
Journal of Organic Chemistry, , vol. 48, # 26 p. 5309 - 5315
反应条件
1: 87 percent / AG 1-X4(OH-) / methanol / 2 h / Ambient temperature 2: 81 percent / NaN3, NH4Cl / 2-methoxy-ethanol; H2O / 2 h / 100 °C 3: H2 / 10percent Pd/C / methanol / 15 h / 2280 Torr View Scheme
参考文献
Journal of Organic Chemistry, , vol. 48, # 26 p. 5309 - 5315
