三丁基(2-噻吩基)锡合成路线 （共 133 条）
反应条件
1-methyl-pyrrolidin-2-one; manganese bromide tetrahydrate; potassium fluoride; para-iodoanisole T=100°C; 8 h; other reagents: p-iodoanisole/CuI/KF, p-iodoanisole/CuI/CsF, p-iodoanisole/MnBr2/LiCl, p-iodoanisole/MnBr2/CsF, iodobenzene/CuI/NaCl;
参考文献
Journal of Organic Chemistry, , vol. 62, # 13 p. 4208 - 4209
反应条件
1-methyl-pyrrolidin-2-one; potassium fluoride; copper(l) iodide T=90°C; 7 h; other organostannanes, other organic iodides, other reagents: CuI/NaCl, CuI/KCl, CuI/LiCl, CuI/CsF, MnBr2/NaCl, MnBr2/KCl, MnBr2/KF, MnBr2/LiCl, MnBr2/CsF, MnCl2*4H2O, MnI2, DMF presence, other temperature and time; Product distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 62, # 13 p. 4208 - 4209
反应条件
Pd2(PPh3)2Cl2 in N,N-dimethyl-formamide
Stille coupling; 16 h; Inert atmosphereHeating;
参考文献
Pietrangelo; Boden; MacLachlan; Wolf
Canadian Journal of Chemistry, 2009 , vol. 87, # 1 SPEC. ISS. p. 314 - 320
反应条件
1-methyl-pyrrolidin-2-one; copper(l) iodide; sodium chloride
T=100°C; 6 h; other reagent: MnBr2, NaCl, N-methylpyrrolidone;
参考文献
Kang, Suk-Ku; Kim, Jae-Sun; Choi, Sang-Chul
Journal of Organic Chemistry, 1997 , vol. 62, # 13 p. 4208 - 4209
反应条件
triphenylphosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=80°C;
参考文献
Lois, Sandrine; Flores, Jean-Charles; Lere-Porte, Jean-Pierre; Serein-Spirau, Francoise; Moreau, Joel J. E.; Miqueu, Karinne; Sotiropoulos, Jean-Marc; Baylere, Patrick; Tillard, Monique; Belin, Claude
European Journal of Organic Chemistry, 2007 , # 24 p. 4019 - 4031
反应条件
palladium diacetate; triphenylphosphine in dimethyl sulfoxide
T=145°C; 0.583333 h; Inert atmosphere; Product distribution / selectivity;
参考文献
ENI S.P.A.; SANTARELLI, Samuele; RICCI, Marco; FUSCO, Roberto
Patent: WO2012/7834 A1, 2012 ;
Location in patent: Page/Page column 11; 17-18 ;
反应条件
bis-triphenylphosphine-palladium(II) chloride in benzene
react. mixt. washed (aq. KF); extn.of org. layer (ether); dried over MgSO4; product isolated by distn. (reduced pressure); acetonylated by chromy. (silica gel);
参考文献
Kosugi; Miyajima; Nakanishi; Sano; Migita
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 10 p. 3383 - 3385
反应条件
bis-triphenylphosphine-palladium(II) chloride in benzene
react. mixt. washed (aq. KF); extn.of org. layer (ether); dried over MgSO4; product isolated by distn. (reduced pressure); acetonylated by chromy. (silica gel);
参考文献
Kosugi; Miyajima; Nakanishi; Sano; Migita
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 10 p. 3383 - 3385
反应条件
tetrakis(triphenylphosphine) palladium(0) in toluene
Stille cross-coupling; Heating;
参考文献
Pinault, Thomas; Cherioux, Frederic; Therrien, Bruno; Suess-Fink, Georg
Heteroatom Chemistry, 2004 , vol. 15, # 2 p. 121 - 126
反应条件
trifuran-2-yl-phosphane; CuDPP; tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran
T=50°C; 7 h;
参考文献
Wittenberg, Ruediger; Srogl, Jiri; Egi, Masahiro; Liebeskind, Lanny S.
Organic Letters, 2003 , vol. 5, # 17 p. 3033 - 3035
