2,2-二甲基丙二酸单乙酯合成路线 （共 19 条）
反应条件
methanol; potassium-salt T=40°C; Electrolysis;
参考文献
Alberti
Gazzetta Chimica Italiana, 1956 , vol. 86, p. 1195,1208
Chem.Abstr., 1959 , p. 18860
反应条件
Reaktion des Kaliumsalzes.Electrolysis;
参考文献
Fichter; Steinbuch
Helvetica Chimica Acta, 1943 , vol. 26, p. 697
参考文献
Fichter; Steinbuch
Helvetica Chimica Acta, 1943 , vol. 26, p. 697
反应条件
Reaktion des Kaliumsalzes.Electrolysis;
参考文献
Fichter; Steinbuch
Helvetica Chimica Acta, 1943 , vol. 26, p. 697
参考文献
Fichter; Steinbuch
Helvetica Chimica Acta, 1943 , vol. 26, p. 697
反应条件
1: SOCl2 / 50 - 55 °C 2: diethyl ether 3: 57 percent / LiAlH4 / tetrahydrofuran / 96 h / Heating View Scheme
参考文献
Huang, Yande; Yu, Jaehoon; Bentrude, Wesley G.
Journal of Organic Chemistry, 1995 , vol. 60, # 15 p. 4767 - 4773
反应条件
thionyl chloride; ammonia
1.) reflux, 1 h, 2.) r.t.;
参考文献
Holmes, Robert R.; Day, Roberta O.; Setzer, William N.; Sopchik, Alan E.; Bentrude, Wesley G.
Journal of the American Chemical Society, 1984 , vol. 106, # 8 p. 2353 - 2358
反应条件
1: 25.9 percent / 1.) thionyl chloride, 2.) anhydrous ammonia / 1.) reflux, 1 h, 2.) r.t.
2: 1.) lithium aluminium hydride, 3.) anhydrous magnesium sulfate / 1.) ethyl ether, reflux, 24 h, 2.) water, r.t., 1 h, 3.) 15 min.
3: 35 percent / triethylamine / ethyl acetate / 120 h / Ambient temperature
View Scheme
参考文献
Holmes, Robert R.; Day, Roberta O.; Setzer, William N.; Sopchik, Alan E.; Bentrude, Wesley G.
Journal of the American Chemical Society, 1984 , vol. 106, # 8 p. 2353 - 2358
反应条件
(i) SOCl2, (ii) /BRN= 773638/, Et3N, benzene; Multistep reaction;
参考文献
Scott,A.I.; Kang,K.
Journal of the American Chemical Society, 1977 , vol. 99, p. 1997 - 1999
