in diethyl ether T=20°C; 4 h; Reagent/catalystSolvent;
参考文献
UNIVERSITE DE BORDEAUX I; Centre National de la Recherche Scientifique; Pucheault, Mathieu Jonathan Damien; Marciasini, Ludovic Daniel Alain; Vaultier, Michel
Patent: EP2684887 A1, 2014 ;
Location in patent: Paragraph 0108; 0109; 0110; 0111 ;
biscyclopentadienyliron(II) in acetonitrile
T=18 - 20°C; 2.5 h; Reagent/catalyst;
参考文献
UNIVERSITE DE BORDEAUX I; Centre National de la Recherche Scientifique; Pucheault, Mathieu Jonathan Damien; Marciasini, Ludovic Daniel Alain; Vaultier, Michel
Patent: EP2684887 A1, 2014 ;
Location in patent: Paragraph 0062 ;
1: 4-methoxy-aniline With tetrafluoroboric acid in water
T=0°C; 0.166667 h;
2: With sodium nitrite in water
T=0°C; 1 h;
3: tBuCH2CH2B(H)NiPr2 With biscyclopentadienyliron(II) in acetonitrile
T=20°C; 2.5 h; Inert atmosphere; Kinetics; Reagent/catalystSolvent;
1.1: sulfuric acid / tetrahydrofuran / 0.25 h / 0 °C
1.2: 0 - 20 °C
2.1: tetrafluoroboric acid / water / 0.17 h / 0 °C
2.2: 1 h / 0 °C
2.3: 2.5 h / 20 °C / |Inert atmosphere
View Scheme
