反应条件
1.1: 173 mg / triethylamine; 4-(dimethylamino)pyridine / CH2Cl2 / 2.75 h / 20 °C
2.1: 82 percent / KOH / H2O; methanol / 1 h / 20 °C
3.1: oxalyl chloride / dimethylformamide; benzene / 1 h / 20 °C
4.1: CH2Cl2 / 2 h / 20 °C
5.1: 115 mg / (PHS)3Sb; air / diethyl ether / 1.5 h / 20 °C
6.1: 79 percent / pyridinium chlorochromate; sodium acetate / CH2Cl2 / 2 h / 20 °C
7.1: 96 percent / diethyl ether / 0.75 h / -78 °C
8.1: 100 percent / tetrabutylammonium fluoride / tetrahydrofuran / 2.5 h / 20 °C
9.1: 54 percent / imidazole; iodine; triphenylphosphine / 2,6-lutidine / benzene; 1,2-dichloro-ethane; H2O / 0.25 h / 80 °C
10.1: 51 percent / p-TsOH / CH2Cl2 / 2.3 h / 20 °C
11.1: 75 percent / p-TsOH; N-(phenylseleno)phthalimide / CH2Cl2 / 6.5 h / 20 °C
12.1: 60 percent / 4-(dimethylamino)pyridine / pyridine / 24 h / 40 °C
13.1: ozone / CH2Cl2 / -78 °C
13.2: 62 percent / pyridine / CH2Cl2; CCl4 / 1.5 h / Heating
View Scheme
参考文献
Prange, Thierry; Rodriguez, Maria S.; Suarez, Ernesto
Journal of Organic Chemistry, 2003 , vol. 68, # 11 p. 4422 - 4431
